In this thesis, photocrosslinked ferrocene-based methacrylate polymers for thin-film cathodes in lithium batteries have been synthesized. Patterned
thin-film electrodes of the ferrocene-based methacrylate polymers are
fabricated by photocrosslinking. The structure and composition of the
photocrosslinkable polymers are characterized by infrared spectra, nuclear
magnetic resonances, and gel permeation chromatography. The result of quartz crystal microbalance shows that the crosslinked polymers prevent the polymers from dissolving into organic electrolytes. The cyclic voltammogram shows the photocrosslinked ferrocene-based methacrylate polymers have a redox couple. The energy capacity of the polymer for lithium batteries is about 40-50 mAh g-1 at a discharge rate of 10 C. The results show that the photocrosslinked ferrocene-based methacrylate polymers also improve the batteries.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0825111-171803 |
| Date | 25 August 2011 |
| Creators | Tseng, Hsueh-Fen |
| Contributors | Shu-chen Hsieh, Jyh-Tsung Lee, Mao-Sung Wu |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0825111-171803 |
| Rights | user_define, Copyright information available at source archive |
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