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Structure and Photoluminescence of Organic Fluorophore / Polycyanate Blends

In contrast to traditional conjugated polymer, the non-conjugated polycyanate
network represents an interesting example to work with. Close packings among the
phenylene and s-triazine rings in polycyanate may introduce £k-£k interaction and
thereby, induce light emission. There is an important relationship between molecular
packing and photo-luminescence properties. To clarify it, we also add aromatic
fluorophore to hopefully alter the packing situation and from the response, further
evaluation can be made.
Detailed molecular packing in the network polycyanate can be evaluated by the
molecular simulation technique. The simulation results for the pure polycyanate show
that the most-likely inter-ring distance is 3 ~ 5

Identiferoai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0720105-113508
Date20 July 2005
CreatorsChiu, Chen-Wei
ContributorsCheng-Lung Chen, Jui-Hung Hsu, Ming Chen, Jin-Long Hong
PublisherNSYSU
Source SetsNSYSU Electronic Thesis and Dissertation Archive
LanguageCholon
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0720105-113508
Rightsrestricted, Copyright information available at source archive

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