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Syntéza pokročilých intermediátov na báze para-bis (2-thienyl) fenylenu so zabudovaným adamantanovým skeletom. Vplyv intramolekulárnych vodíkových väzieb na fotoizomerizáciu. / Synthesis of advanced adamantane containing intermediates based on para-bis (2-thienyl) phenylene. Influence of intramolecular hydrogen bonds on photoisomerization

This diploma thesis describes study and onward synthesis of advanced organic structures with potential application in the field of organic electronics and, in particular, molecular photoswitches. In the theoretical part of the thesis are closely described most commonly used conventional molecular photoswitches with special attention to the influence of the structural modifications on properties and applications of the given derivatives. Next passage is dedicated to study of donor-acceptor systems, as fundamental building blocks for synthesis of advanced derivatives. The possibilities of derivatization with a goal of improving the physicochemical properties of these compounds are also discussed. In the final chapter are proposed modern synthetic methods for preparation of novel materials for organic electronics. This section is connected with an experimental part, where are designed and consequently synthesised 4 novel imine derivatives with dodecyl and adamantyl-ethyl side chain.

Identiferoai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:444541
Date January 2021
CreatorsVeselý, Dominik
ContributorsPospíšilík, Karel, Krajčovič, Jozef
PublisherVysoké učení technické v Brně. Fakulta chemická
Source SetsCzech ETDs
LanguageSlovak
Detected LanguageEnglish
Typeinfo:eu-repo/semantics/masterThesis
Rightsinfo:eu-repo/semantics/restrictedAccess

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