A generalized chemical oscillator has been invented consisting of input and output interfaces to a chemical system, with the appropriate feedback external to the chemical system such that the system oscillates. The oscillation frequency can be made a function of concentration, reaction kinetics, transport phenomena, and other physical properties. The idea was reduced to practice with an electronic system coupled to an electrochemical system, and gave a frequency output linear with concentration for a number of ions in solution. A general mathematical model of the electrochemical system was devised and programmed in FORTRAN on a digital computer, and a mathematical model of the oscillogenic instrument was used to conceptually test the idea. The use of recursive parameter estimation was also considered for this instrument. / Ph. D.
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/71263 |
| Date | January 1986 |
| Creators | Mercure, Peter Kip |
| Contributors | Chemical Engineering, Rony, Peter R., Beex, Aloysius A., Davis, Mark E., Guruswamy, V., McGee, Henry A. Jr., McNair, Harold M. |
| Publisher | Virginia Polytechnic Institute and State University |
| Source Sets | Virginia Tech Theses and Dissertation |
| Language | en_US |
| Detected Language | English |
| Type | Dissertation, Text |
| Format | vi, 427 leaves, application/pdf, application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | OCLC# 23713732 |
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