Common brown colour in natural diamond forms by plastic deformation during storage in the subcontinental lithospheric mantle (SCLM). Dislocation movement generates vacancies, which aggregate into clusters of perhaps 30–60 vacancies. Positron annihilation lifetime spectroscopy (PALS) and electron energy loss spectroscopy (EELS) support such vacancy clusters as the cause of brown colour.
Brief treatment in a high-pressure–high-temperature (HPHT) vessel at 1800–2700 °C can destroy the brown colour. There has been speculation that similar colour removal should occur continuously at depth in the SCLM. Diamonds are stored at 900–1400 °C in the SCLM, according to inclusion thermometry. The effect of temperature on the time required to destroy brown colour has been calculated from published data. The activation energy for the breakup of vacancy clusters is a critical component.
The time required to destroy brown colour in the SCLM is significant at the scale of geological time. Brown diamonds should easily maintain their colour for millions of years during cooler mantle storage at or below about 1000 °C. Warmer temperatures toward the base of the lithosphere may be able to reduce or eliminate brown colour within thousands of years. The survival of brown colour in the lithospheric mantle does not require the colour to be formed late
in the storage history nor does it require metastable storage in the graphite stability field.
Crystal strain is preserved upon loss of brown colour during HPHT treatment. Inhomogeneous crystal strain was measured in 18 natural diamonds using micro-X-ray diffraction (μXRD) χ-dimension peak widths. There is a correlation between strain and depth of brown colour. None of the colourless diamonds examined have high strain, as should be expected for a
diamond that has gained and lost brown colour. This suggests that removal of brown colour is not a common natural occurrence.
Infrared spectroscopy was used to determine nitrogen concentration and aggregation state
in 60 natural diamonds. A loose association was found between brown colour and lower total nitrogen content. Within single diamonds, regions with less nitrogen tend to exhibit more anomalous birefringence due to strain. Colour zoned diamonds tend to have less nitrogen in the darker brown regions. This supports the hypothesis that diamonds with less nitrogen are more susceptible to plastic deformation and the development of brown colour. / Thesis (Master, Geological Sciences & Geological Engineering) -- Queen's University, 2009-09-17 17:10:11.078
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:OKQ.1974/5184 |
| Date | 23 September 2009 |
| Creators | Smith, Evan Mathew |
| Contributors | Queen's University (Kingston, Ont.). Theses (Queen's University (Kingston, Ont.)) |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English, English |
| Detected Language | English |
| Type | Thesis |
| Format | 89600842 bytes, application/pdf |
| Rights | This publication is made available by the authority of the copyright owner solely for the purpose of private study and research and may not be copied or reproduced except as permitted by the copyright laws without written authority from the copyright owner. |
| Relation | Canadian theses |
Page generated in 0.0016 seconds