The diploma thesis deals with radical bulk polymerization of styrene. Recent knowledges about mono- and multifunctional initiators of radical polymerization and coordination polymerization of styrene with metalocene initiators are summarized in theoretical part. Experimental part of diploma thesis is focused on relationship between polymerization conditions and conversion, molecular mass and distribution of molecular mass. Experiments carried out with monofunctional initiators (dibenzoylperoxide, dilauroylperoxide, tert-butylperbenzoate) and with bifunctional initiators (Luperox 101 and Luperox 256). Polymerizations took place at temperatures from 80 to 134 °C, reaction time was from 1 to 24 hours, and pressure was 100 and 500 kPa. Conversion of monomer was determined by gravimetry and infrared spectroscopy. Molecular mass and indexes of polydisperzity were measured by gel permeation chromatography in solutions of polystyrene with tetrahydrofurane at temperature 23 °C.
| Identifer | oai:union.ndltd.org:nusl.cz/oai:invenio.nusl.cz:216622 |
| Date | January 2010 |
| Creators | Pukančíková, Andrea |
| Contributors | Petrůj, Jaroslav, Kučera, František |
| Publisher | Vysoké učení technické v Brně. Fakulta chemická |
| Source Sets | Czech ETDs |
| Language | Czech |
| Detected Language | English |
| Type | info:eu-repo/semantics/masterThesis |
| Rights | info:eu-repo/semantics/restrictedAccess |
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