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Enantiospecific syntheses of cyclophellitol and its analogues from (-)-quinic acid.

by Vincent Wing-Fai Tai. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1993. / Includes bibliographical references (leaves 79-83). / Acknowledgements --- p.i / Contents --- p.ii / Abstract --- p.iii / Abbreviations --- p.iv / Chapter I --- Introduction / Chapter I-1 --- General Background --- p.1 / Chapter I-2 --- Review on Epoxycyclohexanes --- p.2 / Chapter I-3 --- Mechanistic Aspect of Glycosidase Inhibitors --- p.5 / Chapter I-4 --- Previous Synthesis of cyclophellitol and its diastereoisomers 1-4 --- p.12 / Chapter II --- Results and Discussion / Chapter II-l --- General Strategy --- p.19 / Chapter II-2 --- Synthesis of the diol 57 --- p.21 / Chapter II-3 --- Synthesis of the allylic alcohol 54 --- p.25 / Chapter II-4 --- "Synthesis of Cyclophellitol 1 and its (lR,6S)-diastereoisomer 2" --- p.29 / Chapter II-5 --- "Synthesis of the (2S)- and (lR,2S,6S)-diasteroeisomers 3 and 4" --- p.34 / Chapter II-6 --- Comments on the MCPBA Epoxidation --- p.37 / Chapter II-7 --- Synthesis of the Epoxy Analogues of Cyclophellitol 104 and 105. --- p.40 / Chapter II-8 --- Results of biological assays --- p.43 / Chapter III --- Conclusion --- p.48 / Chapter IV --- Experimental --- p.50 / Chapter V --- References --- p.79 / Chapter VI --- Spectra --- p.84

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_319225
Date January 1993
ContributorsTai, Vincent Wing-Fai., Chinese University of Hong Kong Graduate School. Division of Chemistry.
PublisherChinese University of Hong Kong
Source SetsThe Chinese University of Hong Kong
LanguageEnglish
Detected LanguageEnglish
TypeText, bibliography
Formatprint, iv, 90 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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