by Ka-yue Chiu. / The "3" in the title is subscript. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1996. / Includes bibliographical references (leaves 103-110). / ACKNOWLEDGEMENTS --- p.3 / ABBREVIATIONS --- p.4 / ABSTRACT --- p.5 / Chapter I. --- COORDINATION CHEMISTRY OF SmI3 WITH DONOR SOLVENTS --- p.7 / Chapter 1.1. --- Introduction --- p.7 / Chapter 1.2 --- Results and Discussion --- p.21 / Chapter 1.2.A --- Synthesis and Structural Characterization of [trans-SmI2(THF)5][trans- SmI4(THF)2] (1) --- p.21 / Chapter 1.2.B --- Synthesis and Structural Characterization of SmI3(DME)2 (2) --- p.26 / Chapter 1.2.C --- Synthesis and Structural Characterization of [{Sm(H20)3}2{Sm(CH3CN) (H20)3}2{Sm(CH3CN)3(H20)}2(μ3-OH)8(μ6-0)]I8-2H20 (3) --- p.30 / Chapter 1.3 --- Conclusion --- p.38 / Chapter 1.4 --- Experimental Section --- p.39 / Chapter II. --- SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF LANTHANACARBORANES --- p.45 / Chapter II.1 --- Introduction --- p.45 / Chapter II.2 --- Results and Discussion --- p.51 / Chapter II.2.A --- Synthesis and Characterization of closo-Lanthanacarboranes --- p.51 / Chapter II.2.A.i --- Sandwich Type Complexes --- p.51 / Chapter II.2.A.ii. --- Half-Sandwich Type Complexes --- p.62 / Chapter II.2.B --- Synthesis and Characterization of an exo-nido-Samaracarborane --- p.71 / Chapter II.2.B.i. --- Synthesis and Characterization of an exo-nido-[{(C6H5CH2)2C2B9H9} Sm(DME)2]2.DME(18) --- p.77 / Chapter II.3 --- Conclusion --- p.84 / Chapter II.4 --- Experimental Section --- p.85 / REFERENCES --- p.99
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_321857 |
| Date | January 1997 |
| Contributors | Chiu, Ka-yue., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, 110 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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