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Laser-based ion mobility spectrometry for sensing of aromatic compounds

The drift time spectra of polycyclic aromatic hydrocarbons (PAH), alkylbenzenes and alkylphenylethers were recorded with a laser-based ion mobility (IM) spectrometer. The ion mobilities of all compounds were determined in helium as drift gas. This allows the calculation of the diffusion cross sections (Omegacalc) on the basis of the exact hard sphere scattering model (EHSSM) and their comparison with the experimentally determined diffusion cross sections (Omegaexp). These Omegaexp/Omegacalc-correlations are presented for molecules with a rigid structure like PAH and prove the reliability of the theoretical model and experimental method. The increase of the selectivity of IM spectrometry is demonstrated using resonance enhanced multiphoton ionisation (REMPI) at atmospheric pressure, realized by tuneable lasers. The REMPI spectra of nine alkylbenzenes and alkylphenylethers are investigated. On the basis of these spectra, the complete qualitative distinction of eight compounds in a mixture is shown. These experiments are extended to alkylbenzene isomer mixtures.

Identiferoai:union.ndltd.org:Potsdam/oai:kobv.de-opus-ubp:1189
Date January 2004
CreatorsLöhmannsröben, Hans-Gerd, Beitz, Toralf, Luadien, Robert, Schultze, Rainer
PublisherUniversität Potsdam, Mathematisch-Naturwissenschaftliche Fakultät. Institut für Chemie
Source SetsPotsdam University
LanguageEnglish
Detected LanguageEnglish
TypePostprint
Formatapplication/pdf
SourceRemote Sensing in Atmosperic Pollution Monitoring and Control / Allen Chu, James Szykman (eds.). - S. 16 - 24. - (Proceedings of SPIE ; 5547)
Rightshttp://opus.kobv.de/ubp/doku/urheberrecht.php

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