<p> The products of the reaction between oxomethoxodichlorobistriphenylphosphinerhenium(V) and acetylacetone are determined, characterized and correlated in terms of a reaction scheme. A series of rhenium(III) compounds, characteristic of reactions analogous to the one mentioned above, with other β-ketoenols is prepared and characterized. The syntheses and properties of tris-1,1,1-5,5,5-hexafluoropentane-2,4-dionatorhenium(III) and trispentane-2,4-dionatorhenium(III) are described. A new nitrido-rhenium complex, nitridochloro-1,1,1-5,5,5-hexafluoropentane-2,4-dionatobistriphenylphosphinerhenium(V) complex is prepared
and characterized. A synthetic route to pyridine-acetylacetonate
complexes of rhenium is described. </p> / Thesis / Doctor of Philosophy (PhD)
| Identifer | oai:union.ndltd.org:mcmaster.ca/oai:macsphere.mcmaster.ca:11375/17538 |
| Date | 05 1900 |
| Creators | Courrier, William Donald |
| Contributors | Lock, C.J.L., Chemistry |
| Source Sets | McMaster University |
| Language | en_US |
| Detected Language | English |
| Type | Thesis |
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