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Corrole–BODIPY conjugates: enhancing the fluorescence and phosphorescence of the corrole complex via efficient through bond energy transfer

New corrole–BODIPY conjugates have been synthesized in high yield under mild conditions. Upon excitation at the absorption maximum of the BODIPY antenna chromophore, the fluorescence intensity of the free base corrole–BODIPY conjugate increases by ca. 300%, and significant phosphorescence intensity is observed for the iridium(III) complex of the conjugate, while almost no phosphorescence is observed for the parent iridium(III) corrole, due to through-bond energy transfer from the BODIPY antenna-chromophore to the corrole core. / Original publication is available at http://dx.doi.org/10.1039/c5ra07250f / Arbortext Advanced Print Publisher 9.1.510/W Unicode / Acrobat Distiller 8.1.0 (Windows); modified using iText� 5.3.3 �2000-2012 1T3XT BVBA (AGPL-version)

Identiferoai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:rhodes/vital:7268
Date08 June 2015
CreatorsChen, Wei, Zhang, Jianfeng, Mack, John, Kubheka, Gugu, Nyokong, Tebello, Shen, Zhen, Wei Chen
PublisherRoyal Society of Chemistry
Source SetsSouth African National ETD Portal
LanguageEnglish
Detected LanguageEnglish
TypeArticle

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