Structural evolution and its effect on optical absorption/emission behavior of fluorene-thiophene conjugated alternate copolymers and naphthalene-thiophene conjugated alternate copolymers and polystyrene-poly-3octylthiophene-polystyrene triblock copolymer
of upon isothermal heat treatment at elevated temperatures, and the well £k-£k stack at interchain species (ordered aggregates) be formed in dilute solutions and its effect the UV-vis and PL spectra. These conjugated polymer with mono- or disubstituted with alkyl side chain and with alkyl or alkoxyl flexible side-chains. This studied by means of a combination of polarized light microscopy, x-ray diffraction, ultraviolet-visible spectroscopy, light scattering spectroscopy and photoluminescence spectroscopy. According to the results of the experiment, the fluorene-based polymer can be observed emission from order aggregate in the solution state, but not found in naphthalene-based and triblock copolymer.
Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0627103-123838 |
Date | 27 June 2003 |
Creators | Hsieh, Hsi-Chien |
Contributors | R-H Lin, A-C SU, J-L Hong, R-M HO |
Publisher | NSYSU |
Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
Language | English |
Detected Language | English |
Type | text |
Format | application/pdf |
Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0627103-123838 |
Rights | unrestricted, Copyright information available at source archive |
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