Gas phase anion clusters, consisting of solvent molecules hydrogen bonded to halide anions, are characterised by vibrational predissociation spectroscopy using a combination of mass spectrometry and laser spectroscopy. Monitoring changes in the vibrational properties of neutral solvent molecules when they are attached to a halide anion allows one to infer cluster structures. In some cases, the spectra contain rotationally resolved features, so that quantitative structural parameters can be obtained. (For complete abstract open document)
| Identifer | oai:union.ndltd.org:ADTP/245195 |
| Creators | Wild, Duncan Andrew |
| Source Sets | Australiasian Digital Theses Program |
| Language | English |
| Detected Language | English |
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