Application of HOF.CH3CN to the synthesis of glycosyl sulphones

Description

No / A fast, complete and clean conversion of thioglycosides into glycosyl sulfones under mild acidic conditions is described, using the HOF·CH3CN complex at room temperature. This methodology affords glycosyl sulfones in high yields and in excellent purity.

Links & Downloads

1. Ribeiro Morais, G., Humphrey, A.J. and Falconer, R.A. (2008). Application of HOF.CH3CN to the synthesis of glycosyl sulphones. Tetrahedron. Vol. 64, No. , pp. 7426-7431.
2. http://hdl.handle.net/10454/4617
3. https://doi.org/10.1016/j.tet.2008.05.033

Tags

Glycosyl Sulfones

Oxidation

Thioglycosides

Additional Fields

Identifer	oai:union.ndltd.org:BRADFORD/oai:bradscholars.brad.ac.uk:10454/4617
Date	January 2008
Creators	Ribeiro Morais, Goreti, Humphrey, Andrew J., Falconer, Robert A.
Source Sets	Bradford Scholars
Language	English
Detected Language	English
Type	Article, No full-text available in the repository