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Synchronous exfoliation and assembly of graphene on 3D Ni(OH)2 for supercapacitors

Nowadays, new approaches to fabricate high-performance electrode materials are of vital importance in the renewable energy field. Here, we present a facile synthesis procedure of 3D Ni(OH)2/graphene hybrids for supercapacitors via synchronous electrochemical-assisted exfoliation and assembly of graphene on 3D Ni(OH)2 networks. With the assistance of an electric field, the electrochemically exfoliated high-quality graphene can be readily, uniformly assembled on the surfaces of 3D Ni(OH)2. When serving as electrode materials for supercapacitors, the resulting 3D Ni(OH)2/graphene composites exhibited excellent specific capacitance (263 mF cm−2 at 2 mA cm−2), remarkable rate capability and super-long cycle life (retention of 94.1% even after 10 000 continuous charge–discharge cycles), which may be attributed to their highly porous, stable 3D architecture as well as uniform, firm anchoring of ultrathin graphene on their surfaces. Therefore, our approach provides a facile strategy for the large-scale synthesis of high-quality graphene based composites towards various applications.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa.de:bsz:14-qucosa-224917
Date17 July 2017
CreatorsMa, Liguo, Zheng, Maojun, Liu, Shaohua, Li, Qiang, You, Yuxiu, Wang, Faze, Ma, Li, Shen, Wenzhong
ContributorsRoyal Society of Chemistry,
PublisherSaechsische Landesbibliothek- Staats- und Universitaetsbibliothek Dresden
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typedoc-type:article
Formatapplication/pdf
SourceChemical Communications (2016), 52(91), S. 13371-13376. ISSN: 1364-548X. DOI: 10.1039/C6CC07645A.

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