In order to determine the degradation of Naphthenic Acids (NAs) in oil sands process-affected water (OSPW), a series of semi-batch ozonation experiments have been conducted resulting in a maximum reduction of NAs greater than 99%. Compared to the high NAs removal, the reduction of both COD and DOC was much lower under the same conditions. Following ozone treatments of approx. 80 mg/L, the cBOD5 and cBOD5/COD tripled as compared to original OSPW measurements, suggesting ozone-treated OSPW has a higher biodegradability. The ozone treatments also detoxified the OSPW; with an ozone treatment of approx. 100 mg/L, the treated OSPW showed no toxicity using the Mircotox® bioassay. Additionally, the coke-treated OSPW, treated using a coke/water slurry process, was found to be non-toxic with an ozone treatment of approx. 20 mg/L. The results obtained during this study shows the great potential ozonation may offer as a possible water treatment application for oil sands water management. / Environmental Engineering
| Identifer | oai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:AEU.10048/1771 |
| Date | 06 1900 |
| Creators | Hongjing , Fu |
| Contributors | Galmal El-Din, Mohamed (Civil and Environmental Engineering), Smith, Daniel (Civil and Environmental Engineering), Belosevic, Mike (Biological Sciences), Kang, Seoktae (Civil and Environmental Engineering) |
| Source Sets | Library and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada |
| Language | English |
| Detected Language | English |
| Type | Thesis |
| Format | 1567519 bytes, application/pdf |
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