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DEVELOPMENT OF NOVEL ELECTROPHILIC RUTHENIUM(II) AND IRIDIUM(III) COMPLEXES AND THEIR APPLICATIONS AS HOMOGENEOUS CATALYSTS

Our aim was to develop the synthetic potential and reaction chemistry of Ir3+ and Ru2+ electrophiles by preparing well-characterized complexes whose properties are controllable by modification of the ancillary ligand environment Specifically, we prepared a series of ruthenium complexes to serve as selective hydrogenation and hydrogenolysis catalysts of furan derivatives. We also expanded the synthesis of electrophilic Ir3+ di-thiolate complexes. These types of compounds could eventually serve as catalysts precursors for the addition of weak nucleophiles to alkynes and nitriles.

Identiferoai:union.ndltd.org:uky.edu/oai:uknowledge.uky.edu:gradschool_theses-1100
Date01 January 2011
CreatorsKetcham, Ryan R.
PublisherUKnowledge
Source SetsUniversity of Kentucky
Detected LanguageEnglish
Typetext
Formatapplication/pdf
SourceUniversity of Kentucky Master's Theses

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