We have successfully using the exocyclic double bond of tricarbonyliron triene complexes to undergo (2+1) and (4+2) cycloaddition for the rapid construction of spiro[2.5]octane and spiro[5.5]undecane system. These cycloaddition reactions were chemo-, regio-, and stereoselective. Synthetic studies toward Upenamide, Manzamine A and Manzamine J by using 1-cyano-2,4-cyclohexadiene tricarbonyliron complexes were also discussed.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0711105-190002 |
| Date | 11 July 2005 |
| Creators | Han, Jeng-liang |
| Contributors | Chi-Wi Ong, Nein-Chen Chang, Ming-Jung Wu, Chien-Chung Cheng, Ming-Chang P. Yeh |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0711105-190002 |
| Rights | not_available, Copyright information available at source archive |
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