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Approaches toward Spirocompounds Using Tricarbonyliron Complexes

We have successfully using the exocyclic double bond of tricarbonyliron triene complexes to undergo (2+1) and (4+2) cycloaddition for the rapid construction of spiro[2.5]octane and spiro[5.5]undecane system. These cycloaddition reactions were chemo-, regio-, and stereoselective. Synthetic studies toward Upenamide, Manzamine A and Manzamine J by using 1-cyano-2,4-cyclohexadiene tricarbonyliron complexes were also discussed.

Identiferoai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0711105-190002
Date11 July 2005
CreatorsHan, Jeng-liang
ContributorsChi-Wi Ong, Nein-Chen Chang, Ming-Jung Wu, Chien-Chung Cheng, Ming-Chang P. Yeh
PublisherNSYSU
Source SetsNSYSU Electronic Thesis and Dissertation Archive
LanguageCholon
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0711105-190002
Rightsnot_available, Copyright information available at source archive

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