Late transition metal complexes bearing nitrogen-containing ligands may act as catalyst in biotechnology or industrial catalysis. Imidazole is one of the most common biofunctional ligands that play critical roles in meta1loenzymes, since the imidazole moiety of the histidyl residues often constitutes all or part of the binding sites of various transition metal centers.
In this work, some new zinc(II), copper(II) and nickel(II) complexes containing the imidazolate and pyridyl moieties incorporated in the imine (ImPyI) and amine (ImPyA) ligands were obtained. Different methods of crystallization yield crystals of complexes (2), (6), (8), (9), (10), (17) and (18). Subsequent structural analyses revealed their interesting structures. In zinc(II) and nickel(II) complexes, facial isomers were isolated while none of the meridional isomers were observed. Particularly interesting is the zinc(II) complexes where two facial complexes with different geometries were identified. The mixture of the different nitrogen donor groups in the same ligand provides handy comparison of these structural variations due to the different nature of these donor groups. One tridentate ligand with bromide substitution on the imidazolate and a tetradentate ligand with an additional pyridyl group were synthesized as an extension of this work. One crystal structure of each of the corresponding metal complex bearing these ligands is also discussed here. Most metal complexes are consolidated by extensive weak hydrogen bonds among them in the crystal lattices.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0804106-191133 |
| Date | 04 August 2006 |
| Creators | Wang, Hsiao-Ting |
| Contributors | Chang, TH, Michael Y. Chiang, C. W. Ong, Lan-Chang Liang |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0804106-191133 |
| Rights | unrestricted, Copyright information available at source archive |
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