The new series of μ(α, ω)-alkanediyl compounds of ruthenium, [CpRu(CO)₂]₂[μ-(CH₂)ₙ], where n=5-10, have been prepared from Na[CpRu(CO)₂] and the corresponding diiodoalkane. These compounds, which are stable crystalline solids at ambient temperature, have been fully characterised by microanalysis, infrared, ¹H and ¹³C NMR spectroscopy, melting point and mass spectrometry. The new heterodinuclear complex [Cp(CO)₂Fe(CH₂)₄Ru(CO)₂Cp] has been synthesised by the reaction of [CpFe(CO)₂(CH₂)₄I] with Na[CpRu(CO)₂] and characterised by all the above mentioned techniques.
| Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:uct/oai:localhost:11427/21938 |
| Date | January 1988 |
| Creators | Finch, Karol Paula |
| Contributors | Moss, John R, Jackson, Graham Ellis |
| Publisher | University of Cape Town, Faculty of Science, Department of Chemistry |
| Source Sets | South African National ETD Portal |
| Language | English |
| Detected Language | English |
| Type | Master Thesis, Masters, MSc |
| Format | application/pdf |
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