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Crystallographic insights into (CH3NH3)3(Bi2I9): a new lead-free hybrid organic–inorganic material as a potential absorber for photovoltaics

The crystal structure of a new bismuth-based light-absorbing material for the application in solar cells was determined by single crystal X-ray diffraction for the first time. (CH3NH3)3(Bi2I9) (MBI) is a promising alternative to recently rapidly progressing hybrid organic–inorganic perovskites due to the higher tolerance against water and low toxicity. Single crystal X-ray diffraction provides detailed structural information as an essential prerequisite to gain a fundamental understanding of structure property relationships, while powder diffraction studies demonstrate a high degree of crystallinity in thin films.

Identiferoai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:30174
Date17 March 2017
CreatorsEckhardt, Kai, Bon, Volodymyr, Getzschmann, Jürgen, Grothe, Julia, Wisser, Florian M., Kaskel, Stefan
PublisherRoyal Society of Chemistry
Source SetsHochschulschriftenserver (HSSS) der SLUB Dresden
LanguageEnglish
Detected LanguageEnglish
Typedoc-type:article, info:eu-repo/semantics/article, doc-type:Text
Rightsinfo:eu-repo/semantics/openAccess
Relation10.1039/c5cc10455f

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