Content:
A characteristic of leather is that if it is gradually heated in aqueous solution it reaches a temperature where sudden and irreversible shrinkage occurs. This phenomenon is related to the denaturalization of the collagen protein that conforms the hide and is known as leather shrinkage. Specifically, the internal bonds break thus causing a shortening of the skin that can be up to a 35% from its original length.
Accordingly, one of the most used methods to check the quality of the leather tanning process is the determination of the contraction temperature according to the ISO 3380:2015 standard. This method measures the leather shrinkage when constantly increasing the sample temperature. The shrinkage temperature corresponds to the temperature when the sample suddenly contracts. The value of this temperature indicates the degree of collagen stability and therefore, when higher, the leather will have better quality and resistance.
The process of leather shrinkage can be divided in different stages. Several authors discriminate temperature A1 (when the first fibre starts to shrinkage), temperature C (when there is a massive shrinkage) and finally temperature A2 (when the last fibres are contracted individually).
The method that describes the ISO 3380:2015 standard uses a device where the determination of the shrinkage temperature is performed visually by the laboratory technician. Consequently, the method tends to be imprecise and subjective. It should also be noticed that the device proposed by the standard does not allow differentiation between the different stages of the contraction process.
There are other methods to determine leather shrinkage temperature including differential scanning calorimetry, microscopic hot table, thermogravimetric analysis, differential thermal analysis and thermomechanical analysis. All these methods involve complex devices and are only suitable for specialized personnel.
In this work, a new device is developed to precisely measure the leather shrinkage temperature and to distinguish the different contraction stages. In addition, the proposed device is simple, easy to use and inexpensive, which facilitates its use in any industry. The developed system consists basically of a load cell to measure the strength produced by the shrinkage of the leather. With the logged data during the test a strength versus temperature graph is built. By means of its interpretation, the different stages of shrinkage can be determined. Different mathematical analysis of the logged data is proposed to determine the shrinkage stages temperatures, thus achieving a high degree of certainty and repeatability.
Take-Away:
A new device, simple and inexpensive, is developed to precisely measure the leather shrinkage temperature and to distinguish the different contraction stages.
| Identifer | oai:union.ndltd.org:DRESDEN/oai:qucosa:de:qucosa:34127 |
| Date | 03 June 2019 |
| Creators | Morera, Josep Maria, Esteban, Bernat, Baquero, G., Cuadros, R. |
| Contributors | International Union of Leather Technologists and Chemists Societies |
| Publisher | Verein für Gerberei-Chemie und -Technik e. V., Forschungsinstitut für Leder und Kunststoffbahnen (FILK) gGmbH |
| Source Sets | Hochschulschriftenserver (HSSS) der SLUB Dresden |
| Language | English |
| Detected Language | English |
| Type | info:eu-repo/semantics/publishedVersion, doc-type:conferenceObject, info:eu-repo/semantics/conferenceObject, doc-type:Text |
| Rights | info:eu-repo/semantics/openAccess |
| Relation | urn:nbn:de:bsz:14-qucosa2-340872, qucosa:34087 |
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