Permittivity values of a co-solvent system decrease with increasing temperature and decrease as mole fraction of water decreases. Fit to a cubic polynomial, the coefficients can be used to determine relative permittivity of the co-solvent system knowing temperature and mole fraction. A Brookhaven Instruments BI 870 Dielectric Meter was used. Pure water from 15.0 to 55.0 °C was measured to validate the method. Solutions of acetone and tetrahydrofuran were measured from 15.0 to 55.0 °C. A cubic polynomial fit was used to determine the polynomial coefficients for determining permittivity as a function of temperature and mole fraction. These coefficients may also be used to interpolate the dielectric constant between temperatures. Literature values for acetonitrile, 1,4-dioxane, methanol, ethanol, isopropanol and N,N-dimethylformamide in water were used to determine the polynomial coefficients.
Identifer | oai:union.ndltd.org:ETSU/oai:dc.etsu.edu:etsu-works-12049 |
Date | 01 December 2017 |
Creators | Scott, Dane W., Wiseman, Floyd L., Cooper, William C., Alseiha, Yahya S. |
Publisher | Digital Commons @ East Tennessee State University |
Source Sets | East Tennessee State University |
Detected Language | English |
Type | text |
Source | ETSU Faculty Works |
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