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Analysis and processing issues of plastic color mismatch

Color is a visual characteristic which imparts the ability to categorize different
objects. When light strikes an object, there are three possibilities as to what can happen.
The light may be reflected, refracted or scattered. Human perception of color is due to a
combination of these. Plastics are polymeric materials. Polymers are generally colorless
and need colorants in order to have some color. One or more pigments in certain ratios
can be used to give a specific color to plastics. Slight variations in the proportions of
either of the used pigments, or their dispersion, may result in a color that is different from
the desired one. There can also be many other reasons for color mismatch such as
processing or degradation effects.
This study utilized the historical data records of SABIC IP to look at effects of
changing Grade on color (i.e. when the same color is produced from resin blends which
may have different amounts of resins, pigments or additives). These records were also
used to study effects of change in screw diameter and configuration on color (i.e. when
the same grade of a color is produced on two different production lines, different screw
diameters and configurations).
The effects of the processing parameters on the colors were also investigated by
carrying out experiments using a twin screw extruder at SABIC IP’s plant in Cobourg.
Resins, pigments and additives were dry blended and extruded while being subjected to
different processing conditions. Three processing parameters, namely temperature, rpm
and feed-rate, were chosen for the study. A three level factorial design of experiments
was used. An analysis of variance (ANOVA) has been utilized to find the effects of
individual parameters on color and the interaction between two parameters and their
cumulative effect on color. / UOIT

Identiferoai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:OOSHDU.10155/147
Date01 May 2011
CreatorsRabbani, Musharaf
ContributorsRizvi, Ghaus
Source SetsLibrary and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada
LanguageEnglish
Detected LanguageEnglish
TypeThesis

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