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Subsolidus phase relations in the systems Ag-Sb and Ag-Sb-S.

The phase boundaries as obtained in the Ag-Sb system are as follows: Sb-rich solvus of ε phase at 500, 450, 400 and 350, and 300°C is 18.2, 17.7, 17.75 and 17.7 weight per cent Sb respectively. Ag-rich solvus of ε' phase (dyscrasite) at 500, and 450, 400, 350, 300° C is 22.5 and 22.9 weight per cent Sb respectively. Sb-rich solvus of ε' phase at 500, 450, 400 and 350°C is 27.2 weight per cent Sb and at 300°C is 26.9 weight per cent Sb. No inversion of ε’ to ε” at about 440-449°C was observed. The homogeneity range of pyrargyrite is probably less than 1 weight per cent Sb2S3 at 400° C and in miargyrite less than 0.6 weight percent Sb2S3 at 400°C.

Identiferoai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:QMM.115268
Date January 1963
CreatorsSomanchi, Sitaramayya.
ContributorsClark, L. (Supervisor)
PublisherMcGill University
Source SetsLibrary and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada
LanguageEnglish
Detected LanguageEnglish
TypeElectronic Thesis or Dissertation
Formatapplication/pdf
CoverageMaster of Science. (Department of Earth Sciences.)
RightsAll items in eScholarship@McGill are protected by copyright with all rights reserved unless otherwise indicated.
Relationalephsysno: NNNNNNNNN, Theses scanned by McGill Library.

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