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Physical controls on water migration in above ground elemental sulphur blocks

Elemental sulphur (S0) is produced from processing bitumen from the oil sands region, Alberta. Long term storage of this S0 is under consideration. The objective of the current study was to determine the controls on water migration in variably saturated S0 blocks. Based on visual observations of S0 blocks, they were characterized as a hydrophobic fractured porous media. Thus, measurements of the hydraulic characteristics, including porosity (n) and hydraulic conductivity (K) of the matrix and the fractured media, were undertaken. These data were used to create characteristic relationships of unsaturated K (Kunsat) and volumetric moisture content (è) change with change in positive injection pressure (Ø).<p>Analyses showed that the mean total matrix n (nm) was 0.094 ± 0.035 (n = 280), the mean n available for water migration (na) was 0.065 ± 0.044 (n = 8) and the mean (geometric) K for the matrix was 2.0 x 10-6 ± 2.1 x 10-6 ms-1. In the case of vertical fractures, the aperture frequencies were measured to be 2.5, 10.0 and 21.0 m-1 for fractures with apertures > 1.4, 1.4 to 0.6 and < 0.6 mm respectively while the frequency of horizontal fractures, were measured to be 1.7 and 3.7 m-1 for with apertures > 1.4, and < 1.4 mm respectively. The fracture n (nf) was determined to be 0.0135. è Ø relationships were determined for both the fractured and non fractured media. From these plots, water entry values of 9 mm and 1 m were determined for the fracture pore space and the matrix pore space, respectively.<p>Simulations of packer tests resulted in a bulk saturated K (Kb) values ranging from 8.5 x 10-5 to 2 x 10-4 ms-1 above 9 m depth and 3 x 10-6 to 1.5 x 10-5 ms-1 below 9 m depth. Coupled Kunsat Ø and è Ø relationships were used to conceptually describe water migration in S0 blocks under different precipitation and mounding conditions. These plots also showed that the Kb is dominated by the fractures.

Identiferoai:union.ndltd.org:LACETR/oai:collectionscanada.gc.ca:SSU.etd-04252007-114610
Date25 April 2007
CreatorsBonstrom, Kristie
ContributorsBarbour, S. Lee, Ansdell, Kevin M., Hendry, M. Jim
PublisherUniversity of Saskatchewan
Source SetsLibrary and Archives Canada ETDs Repository / Centre d'archives des thèses électroniques de Bibliothèque et Archives Canada
LanguageEnglish
Detected LanguageEnglish
Typetext
Formatapplication/pdf
Sourcehttp://library.usask.ca/theses/available/etd-04252007-114610/
Rightsunrestricted, I hereby certify that, if appropriate, I have obtained and attached hereto a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dissertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. I hereby grant to University of Saskatchewan or its agents the non-exclusive license to archive and make accessible, under the conditions specified below, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation or project report. I also retain the right to use in future works (such as articles or books) all or part of this thesis, dissertation, or project report.

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