The influence of sintering temperature and hold time on the microstructure of of a microwave sintered LSM-YSZ (lanthanum strontium manganate - yttria stabilized zirconia) cathode has been studied. For experimental purposes, a microwave furnace was designed and fabricated with a closed loop temperature feedback control system. A type R thermocouple was used to provide accurate temperature readings inside the microwave cavity. An Allen Bradley Micrologix PLC was used to control the system. This furnace was used as a test bed for experiments involving the rapid sintering of solid oxide fuel cell (SOFC) materials. The SOFC specimens were made by depositing LSM-YSZ cathode material onto YSZ-8 electrolyte buttons. The specimens were sintered for a variety of temperatures and hold times. The microstructure obtained through microwave sintering showed equal or better pore size distribution as compared to those obtained through conventional sintering. The sintered structure was found to be less dense and to contain smaller pores as the sintering temperature was reduced to 1100ËC or lower. Rapid sintering of SOFC materials has potential advantages in terms of SOFC performance and offers potential energy savings when compared with conventional sintering. This research has demonstrated the feasibility of rapid sintering of porous SOFC materials. The next step is to optimize the microwave sintering schedule with respect to the electrical performance and the long term stability of the SOFC.
| Identifer | oai:union.ndltd.org:NCSU/oai:NCSU:etd-05092008-144010 |
| Date | 13 May 2008 |
| Creators | Kapoor, Abhishek Surinder |
| Contributors | Dr. Denis R. Cormier, Dr. Ola L.A. Harrysson, Dr. Carl F. Zorowski |
| Publisher | NCSU |
| Source Sets | North Carolina State University |
| Language | English |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://www.lib.ncsu.edu/theses/available/etd-05092008-144010/ |
| Rights | unrestricted, I hereby certify that, if appropriate, I have obtained and attached hereto a written permission statement from the owner(s) of each third party copyrighted matter to be included in my thesis, dis sertation, or project report, allowing distribution as specified below. I certify that the version I submitted is the same as that approved by my advisory committee. I hereby grant to NC State University or its agents the non-exclusive license to archive and make accessible, under the conditions specified below, my thesis, dissertation, or project report in whole or in part in all forms of media, now or hereafter known. I retain all other ownership rights to the copyright of the thesis, dissertation or project report. I also retain the right to use in future works (such as articles or books) all or part of this thesis, dissertation, or project report. |
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