Flash vacuum pyrolysis (FVP) of 2-(azidomethyl)indole, via a nitrene intermediate gave 1,3,5-tri-2-indolyl-2,4-diaza-1,4-pentadiene as the main product. By the same route, FVP of 3-(azidomethyl)pyridine produced 1,3,5-tri-2-pyridyl-2,4-diaza-1,4-pentadiene.On the other hand, FVP of (2-azidoethyl)benzene gave 1,2-diphenylethane and 3,5-diphenylpyridine as the pyrolysis product.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0627100-115713 |
| Date | 27 June 2000 |
| Creators | Lee, Hsin-Chen |
| Contributors | Mou-Yung Yeh, Nein-Chen Chang, Chin-Hsing Chou |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0627100-115713 |
| Rights | unrestricted, Copyright information available at source archive |
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