Pressureless-sintering of non-stoichiometric barium titanate (BaTiO3) powder of TiO2-excess compositions has been investigated. Crystalline phases were analysed by X-ray diffractometry. Attention has been paid to the analysis of the corresponding sintered microstructure by adopting scanning and transmission electron microscopy.
Large plate-like grains grown abnormally containing {111} double twin lamellae are commonly found in low-temperature (1332oC) sintered BaTiO3, by presence of a liquid phase, or by twinning, or as discussed in this experiments by partial dislocations.
Samples were sintered in air at 1250oC for 1¡B4 and 50 h. In this respect, the emphasis is discussed about the role of the partial dislocations in the early stage of twin formation. Both analytic dislocations exist on the {111} double twin lamellae within abnormal grain and the interface between abnormal grain and normal grain.
In the experimental process, dislocation type with the Burgers vector ‹110› and ‹112› has been found except for the ‹111›. For the Burgers vector ‹110› in the perovskite structure, it is possible to envisage that edge dislocations with [100] Burgers vector can be dissociated in their climb plane ([100] ¡÷ 1/2[101] + 1/2[10 ]). Moreover, the perovskite structure has been deformed form ‹110› dislocation (perfect dislocation). Oppositely, the [112] Burgers vector has been formed both partial dislocation type and perfect dislocation type. For sintering at 50 h, we can conjecture the grain growth mold by Shockley or Frank partial dislocation affect on the macroscopic step.
Experimental results show that Shockley and Frank partial dislocations have not been found on the {111} double twin lamellae.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0707106-120331 |
| Date | 07 July 2006 |
| Creators | Chan, Yueh-lin |
| Contributors | Y.C. Wu, M.H. Lin, Hong-Yang Lu |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0707106-120331 |
| Rights | unrestricted, Copyright information available at source archive |
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