ABSTRACT
Hydrophobic organic pollutants (HOPs) are in general characterized by high toxicity, long environmental half-life and high bio-accumulation factors. Due to their hydrophobicity, HOPs tend to sorb onto particles in environment. The influence of the dissolved organic matters (DOMs) on the sorption partition coefficient is observed because of their interactions with HOPs. This binding between DOM and HOPs increases apparent solubility and mobility of the HOPs in natural aquatic system. On the purpose of obtaining data closer to the real world, many aquatic factors, such as the concentration and types of DOM, pH value and ionic strength, are studied intensively recently.
There are many studies about the mechanisms in the association of DOM and HOPs. Most of them assume achievement of equilibrium in their measurement. Recently, it was reported (Engebretson and von Wandruszka, 1998) that slow, revering, and even oscillating kinetics are observed. It is great concern and interest to those related studies in literatures. Complicated kinetic may in fact be a cause of the reproducibility problems for measurements of HOPs associated with both humic acid and metals. As such, by monitoring fluorescence intensity, we investigate the equilibrium kinetic of pyrene in HA solutions.
In this study, results show that there are two stages of the fluorescence intensity after pyrene spiked into HA solutions: First, the fluorescence intensity decreases steeply due to the first dispersion of pyrene and the reaction of pyrene and HA (the front is dominance). Secound, fluorescence intensity decreases gently because of wall-effect. The dispersion rate of pyrene in HA solutions is difference with HA molecular size and quantity. As the ionic strength rising, cations reacting with specific binding sites on HA, the molecules¡¦ configuration of HA is changed, and less obstruct for dispersing of pyrene. It works as well as little molecular quantity. For second stage when ionic strength rising, wall- associations is less because of the hydrophobic-binding of pyrene and LHA is more stronger.
Furthermore, it is not observed the ¡§migration¡¨ of Mg2+ within the LHA molecular structure as described by Engebretson and von Wandruszka .The reasons that make different results may depend on the species of humic acid. Therefore, the observations of Engebretson and von Wandruszka could not be used directly questioning those results in literatures.
In addition, the effects of various cations (Mg2+, Ca2+and Sr2+) on Kdom are studied. It is believed different cation reacts with different specific binding sites on HA. As such, both charge density and affinity of cation with specific binding sites on HA should be considered in discussing the effects of metal ionic on the binding constants between PAHs and DOM.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0717101-180240 |
| Date | 17 July 2001 |
| Creators | Shen, Da-Chia |
| Contributors | Wei-Hsien Wang, Jen-Fon Jen, Sun-Zo Lee, Chon-Lin Lee |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0717101-180240 |
| Rights | off_campus_withheld, Copyright information available at source archive |
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