In this study, we used different ways to synthetize four-coordinate
zinc(II) and nickel(II) complexes with optically active Schiff base offering N2S2 coordination, i.e. N,N'-Bis(2-thiobenzylidene)-l,2-(R,R)cycholhexyl- enediaminatozinc(II) (1) and N,N'-Bis(2-thiobenzylidene)-l,2-(R,R)cychol-
hexylenediaminatonickel(II) (2). We obtained the crystal structure of 2 and
the pyridine adduct of 1, N,N'-Bis(2-thiobenzylidene)-l,2-(R,R)cycholhexylenediaminopyridylzinc(II) (1¡DPy). Coordination geometry around Zn atom in 1¡DPy is a distorted trigonal bipyramid. These structures were compared with the N2O2 stuctural analogues reported in the literature. We hope these chiral complexes can make contribution to the enzyme model studies in the future.
| Identifer | oai:union.ndltd.org:NSYSU/oai:NSYSU:etd-0830111-181102 |
| Date | 30 August 2011 |
| Creators | Yang, Shin-Ying |
| Contributors | Tsu-Hsin Chang, Michael Yen-Nan Chiang, Po-Chiao Lin, Sodio Chin-Neng Hsus |
| Publisher | NSYSU |
| Source Sets | NSYSU Electronic Thesis and Dissertation Archive |
| Language | Cholon |
| Detected Language | English |
| Type | text |
| Format | application/pdf |
| Source | http://etd.lib.nsysu.edu.tw/ETD-db/ETD-search/view_etd?URN=etd-0830111-181102 |
| Rights | user_define, Copyright information available at source archive |
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