En el presente trabajo describimos el estudio de estas reacciones aplicadas a la preparación de derivados del sistema TpW (CO)z -L (L =ligando organometálico con elementos del IV grupo principal), con el objeto de comparar el componarniento del sistema del tungsteno con el del molibdeno, en parte estudiado por nosotros anteriormente. / We report the reactions of TpW(COh X (Tp = h7-C7H 7, X = Br, 1)with thc anionic species MPh3 - (Ph = C6 Hs ; M= Ge, Sn, Pb) leading to thesubstitution products TpW(C0hMPh3 (3). The compound 3d (M= Pb) couldnot be isolated due to its instability and was only detected spcctroscopically;3b (M= Ge) and 3c (M = Sn) were isolated as red crystals and caracterizedthrough elemental analysis and spectrometry (IR, 1H-NMR and MS).The reduction of TpW(COhl with Na/Hg in THF leads to the an10n[TpW (COhr (1), which also reacts with MPh3- (M = Si, Ge, Sn) forming3a (M = Si), 3b and 3c; 3a was detected only spectroscopically.
| Identifer | oai:union.ndltd.org:PUCP/oai:tesis.pucp.edu.pe:123456789/101310 |
| Date | 25 September 2017 |
| Creators | Zahedi, Farhad, Korswagen, Richard, Ziegler, Manfred L. |
| Publisher | Revista de Química |
| Source Sets | Pontificia Universidad Católica del Perú |
| Language | Español |
| Detected Language | English |
| Type | Artículo |
| Format | |
| Source | Revista de Química; Vol. 3, Núm. 1 (1989); 5-20 |
| Rights | Artículo en acceso abierto, Attribution 4.0 International, https://creativecommons.org/licenses/by/4.0/ |
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