The ground state electron wavefunction of some molecules has a non-zero angular momentum about the internuclear axis. Molecular rotational momentum can couple with this angular momentum, splitting the energy degeneracy of the two directions of motion about the internuclear axis. Performing a Born-Oppenheimer approximation of such a system will break the relevant energy degeneracy at eighth order. This degeneracy breaking is known as L-doubling. / Master of Science
| Identifer | oai:union.ndltd.org:VTETD/oai:vtechworks.lib.vt.edu:10919/30958 |
| Date | 05 February 1999 |
| Creators | Humfeld, Keith Daniel |
| Contributors | Physics, Schmittmann, Beate, Williams, Clayton D., Hagedorn, George A. |
| Publisher | Virginia Tech |
| Source Sets | Virginia Tech Theses and Dissertation |
| Detected Language | English |
| Type | Thesis |
| Format | application/pdf |
| Rights | In Copyright, http://rightsstatements.org/vocab/InC/1.0/ |
| Relation | KDHETD1.PDF |
Page generated in 0.0027 seconds