Batch and column experiments were performed to investigate the adsorption of bacteriophage MS-2 to silica at pH 5. Linear isotherm analysis of batch experiment data gave partition coefficient (KP) estimates of 270 cm³/g and 580 cm³/g for 4°C and 24°C, respectively. Breakthrough-type column experiments indicated that sorption and desorption were slow, as evidenced by a slow approach to breakthrough and tailing of the desorption limb. A non-equilibrium advection-dispersion model with all adsorption sites on the silica assumed to be kinetically controlled was used to model the column data. The model-generated parameters yielded Kp estimates 1000-fold smaller than those given by isotherm analysis and indicated that the time scale for desorption is on the order of 1-6 hours.
| Identifer | oai:union.ndltd.org:arizona.edu/oai:arizona.openrepository.com:10150/277019 |
| Date | January 1989 |
| Creators | Stocking, Kristin, 1959- |
| Contributors | Bales, Roger C. |
| Publisher | The University of Arizona. |
| Source Sets | University of Arizona |
| Language | en_US |
| Detected Language | English |
| Type | text, Thesis-Reproduction (electronic) |
| Rights | Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author. |
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