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Highly fluorinated quinolines

Initial direct chlorination of quinoline in the presence of aluminium trichloride, and subsequent treatment of the tetra- and pentachloroquinolines formed with phosphorus pentachloride at elevated temperatures gave heptachloroquinoline in high yield. Earlier attempts to convert quinoline directly to heptachloroquinoline using either a mixture of sulphuryl chloride, aluminium trichloride and sulphur monochloride, or phosphorus pentachloride gave mixtures of highly chlorinated quinolines which were difficult to purify.

Identiferoai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:585766
Date January 1966
CreatorsHole, Michael
PublisherDurham University
Source SetsEthos UK
Detected LanguageEnglish
TypeElectronic Thesis or Dissertation
Sourcehttp://etheses.dur.ac.uk/8847/

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