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Highly fluorinated quinolines

Initial direct chlorination of quinoline in the presence of aluminium trichloride, and subsequent treatment of the tetra- and pentachloroquinolines formed with phosphorus pentachloride at elevated temperatures gave heptachloroquinoline in high yield. Earlier attempts to convert quinoline directly to heptachloroquinoline using either a mixture of sulphuryl chloride, aluminium trichloride and sulphur monochloride, or phosphorus pentachloride gave mixtures of highly chlorinated quinolines which were difficult to purify.
Date January 1966
CreatorsHole, Michael
PublisherDurham University
Source SetsEthos UK
Detected LanguageEnglish
TypeElectronic Thesis or Dissertation

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