Mixtures of iodine pentafluoride and iodine, and bromine trifluoride and bromine have been shown to behave as iodine monofluoride and bromine monofluoride respectively in their reactions with fluoro-olefins. Several fluoro-olefins have been used and excellent yields of the corresponding iodo- or bromofluoroalkanes obtained. A similar reaction, using a mixture of bromine and chlorine as a source of bromine chloride, has also been investigated. Reactions of iodine monochloride and iodine monobromide with chlorotrifluoroethylene previously described in the literature, were reinvestigated and disclosed a discrepancy with the previous report.
| Identifer | oai:union.ndltd.org:bl.uk/oai:ethos.bl.uk:600863 |
| Date | January 1961 |
| Creators | Savory, John |
| Publisher | Durham University |
| Source Sets | Ethos UK |
| Detected Language | English |
| Type | Electronic Thesis or Dissertation |
| Source | http://etheses.dur.ac.uk/10307/ |
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