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Part I. The chemistry of a planar cyclooctatetraene derivative fused to phenanthrene ring: and Part II. Regiospecific synthesis of 2,3-disubstituted and 2,3,5-trisubstituted furans from 2,4-bis(trimethylsilyl)furan. / Chemistry of a planar cyclooctatetraene derivative fused to phenanthrene ring / Part II. Regiospecific synthesis of 2,3-disubstituted and 2,3,5-trisubstituted furans from 2,4-bis(trimethylsilyl)furan / Regiospecific synthesis of 2,3-disubstituted and 2,3,5-trisubstituted furans from 2,4-bis(trimethylsilyl)furan

by Chun-yip Leung. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1993. / Includes bibliographical references (leaves 72-76). / Acknowledgements --- p.1 / Chapter Part 1). --- The Chemistry of A Planar Cyclooctatetraene Derivatives Fused to Phenanthrene Ring --- p.2 / Chapter (I). --- Abstract --- p.2 / Chapter (II). --- Introduction --- p.3 / Chapter (III). --- Results and Discussion --- p.9 / Chapter (IV). --- Conclusion --- p.18 / Chapter (V). --- Experimental Section --- p.19 / Chapter Part 2). --- "Regiospecific Synthesis of 2,3-Disubstituted and 2,3,5-Trisubstituted Furans from 2,4-Bis(trimethyl- silyl)furan" --- p.28 / Chapter (I). --- Abstract --- p.28 / Chapter (II). --- Introduction --- p.29 / Chapter (A). --- Reactions of Furan --- p.29 / Chapter (1). --- Reactions with Electrophiles --- p.29 / Chapter (2). --- Reactions with Nucleophiles --- p.30 / Chapter (3). --- Cycloaddition Reactions --- p.31 / Chapter (B). --- Synthesis of Polysubstituted Furans --- p.32 / Chapter (1). --- By Ag(I)-Catalyzed Cyclization --- p.33 / Chapter (2). --- By Base-Catalyzed Isomerization of Alkynyloxiranes --- p.33 / Chapter (3). --- By Base-Catalyzed Cyclization- Isomerization of γ-Alkynyl Allylic Alcohol --- p.36 / Chapter (4). --- "By Palladium-Catalyzed Coupling of 2- Propargyl-l,3-dicarbonyl Compounds and Vinylic, Aryl Triflates or Halide" --- p.36 / Chapter (5). --- "From α,β-Unsaturated Ketones" --- p.38 / Chapter (C). --- Recent Achievement --- p.39 / Chapter (III). --- Results and Discussion --- p.44 / Chapter (A). --- "Attempted Synthesis of 2,4-Disubstituted Furans" --- p.44 / Chapter (B). --- "Synthesis of 2,3,5-Trisubstituted Furans" --- p.45 / Chapter (1). --- Synthesis of 2-benzyl-3-m-anisyl-5- p-tolyl-furan (30) --- p.45 / Chapter (2). --- Synthesis of 2-benzyl-3-trans-hexen- l-yl-5-p-tolyl-furan (31) --- p.51 / Chapter (3). --- "Synthesis of 2-(3,5-dimethyl)benzyl-3- p-methoxycarbonylbenzyl-5-hexyl- furan (32)" --- p.52 / Chapter (4). --- "Synthesis of 2-benzyl-3-[3,4-(methyl- enedioxy)]benzyl-furan (33)" --- p.57 / Chapter (IV). --- Conclusion --- p.60 / Chapter (V). --- Experimental Section --- p.61 / References --- p.7 2 / List of Spectra --- p.7 7 / Spectra --- p.7 9

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_319183
Date January 1993
ContributorsLeung, Chun-yip., Chinese University of Hong Kong Graduate School. Division of Chemistry.
PublisherChinese University of Hong Kong
Source SetsThe Chinese University of Hong Kong
LanguageEnglish
Detected LanguageEnglish
TypeText, bibliography
Formatprint, ii, 104 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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