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Synthesis of cumulated and conjugated trienes, polyenes and related natural products.

by Xiao-Ping Cao. / Thesis (Ph.D.)--Chinese University of Hong Kong, 1996. / Includes bibliographical references (leaves 119-126). / Acknowledgement --- p.i / Contents --- p.ii / List of Schemes --- p.iv / List of Tables and Figures --- p.v / List of Spectra --- p.vi / Abstract --- p.ix / Chapter Chapter 1. --- Introduction --- p.1 / Chapter Chapter 2. --- "1,2,3-Butatrienes" / Chapter 2.1. --- "Preparation of 1,2,3-Butatrienes" --- p.4 / Chapter 2.2. --- Our Synthetic Approach --- p.9 / Chapter 2.3. --- Results and Discussion --- p.10 / Chapter Chapter 3. --- "1,3,5-Hexatrienes" / Chapter 3.1. --- "Preparation of 1,3,5-Hexatrienes" --- p.16 / Chapter 3.2. --- Results and Discussion / Chapter 3.2.1. --- Preparation of Hexatrienes Using the Ramberg-Backlund Reaction --- p.24 / Chapter 3.2.2. --- Preparation of Stereoisomerically Pure Diallylic Sulfides and Sulfones --- p.29 / Chapter 3.2.3. --- The Stereochemistry of the Ramberg-Backlund Rearrangement of Diallylic Sulfones --- p.34 / Chapter 3.2.4. --- Effect of Solvent and Temperature on the Stereochemistry of the Newly Formed Double Bond --- p.38 / Chapter 3.2.5. --- Total Synthesis of Galbanolenes --- p.39 / Chapter 3.3. --- Conclusions --- p.41 / Chapter Chapter 4. --- Enediynes / Chapter 4.1. --- "Preparation of 3-Ene-l,5-diynes" --- p.42 / Chapter 4.2. --- Results and Discussion --- p.48 / Chapter Chapter 5. --- "1,3,5,7-Octatetraenes" / Chapter 5.1. --- "Preparation of 1,3,5,7-Octatetraenes" --- p.53 / Chapter 5.2. --- "Preparation of 1,3,5,7-Octatetraenes Using the Ramberg-Backlund Reaction" --- p.57 / Experimental --- p.64 / References --- p.119 / List of Publications Based on Research Reported in This Thesis --- p.127 / Spectra --- p.128

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_321621
Date January 1996
ContributorsCao, Xiao-Ping., Chinese University of Hong Kong Graduate School. Division of Chemistry.
PublisherChinese University of Hong Kong
Source SetsThe Chinese University of Hong Kong
LanguageEnglish
Detected LanguageEnglish
TypeText, bibliography
Formatprint, ix, 171 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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