by Chi Ching Mak. / Thesis (Ph.D.)--Chinese University of Hong Kong, 1995. / Includes bibliographical references (leaves 122-130). / Contents --- p.i / Acknowledgments --- p.iii / Abstract --- p.iv / Abbreviations --- p.v / List of publications originated from this thesis --- p.vi / Chapter I --- Introduction to Dendrimer Chemistry / Chapter I-1 --- Background --- p.1 / Chapter I-2 --- Comparison of Dendrimer and Linear Polymer --- p.6 / Chapter I-3 --- Synthesis --- p.8 / Chapter I-3-1 --- Divergent-growth Approach --- p.8 / Chapter I-3-2 --- Convergent-growth Approach --- p.10 / Chapter I-3-3 --- Accelerated Approach --- p.11 / Chapter II --- Functional Dendrimers --- p.14 / Chapter III --- Optically Active Dendrimers / Chapter III-1 --- Background --- p.18 / Chapter III-2 --- Architecture of Tartaric Acid-based Optically Active Dendrimers --- p.23 / Chapter III-3 --- Results and Discussion --- p.24 / Chapter III-3-1 --- Syntheses and Structure Elucidations of all (L)-Tartaric Acid-based Dendrimers 41 and 42 --- p.24 / Chapter III-3-2 --- Syntheses and Structure Elucidations of Optically Active Layer-block Dendrimers 43 and 44 --- p.29 / Chapter III-3-3 --- Structure-Optical Rotation Relationships --- p.33 / Chapter III-3-4 --- "Syntheses and Characterization of Higher Generation, Optically Active Dendritic Fragments" --- p.37 / Chapter III-3-5 --- Conclusions --- p.43 / Chapter IV --- Catalytic Dendrimers / Chapter IV-1 --- Background --- p.44 / Chapter IV-2 --- Syntheses and Characterization of Dendritic Bis(oxazoline) Copper(II) Catalyst --- p.47 / Chapter IV-2-1 --- Architecture --- p.47 / Chapter IV-2-2 --- Syntheses of the Bis(oxazoline) Core Precursors --- p.49 / Chapter IV-2-3 --- Syntheses of the Achiral Dendritic Sectors --- p.51 / Chapter IV-2-4 --- Syntheses of Dendritic Ligands --- p.52 / Chapter IV-3 --- Kinetics and Selectivity of Dendritic Bis(oxazoline)-Copper(II) Complex Catalyzed Diels-Alder Reaction --- p.55 / Chapter IV-3-1 --- Introduction --- p.55 / Chapter IV-3-2 --- Reaction Mechanism and Reactivity Kinetics --- p.56 / Chapter IV-3-3 --- Substrate Selectivity --- p.63 / Chapter IV-4 --- Syntheses and Properties of Optically Active Dendritic Bis(oxazoline) Ligands and Their Copper(II) Complexes Catalysts --- p.65 / Chapter IV-4-1 --- Background --- p.65 / Chapter IV-4-2 --- Syntheses and Characterization of Chiral Dendritic Bis(oxazoline) Ligands 109-112 --- p.67 / Chapter IV-4-3 --- Chiroptical Properties --- p.72 / Chapter IV-4-4 --- Enantioselectivity of the Metal-catalyzed Diels-Alder Reaction --- p.73 / Chapter IV-4-5 --- Conclusions --- p.74 / Chapter V --- Summary --- p.75 / Chapter VI --- Experimental --- p.77 / References --- p.122 / Spectra --- p.131
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_321656 |
| Date | January 1995 |
| Contributors | Mak, Chi Ching., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Publisher | Chinese University of Hong Kong |
| Source Sets | The Chinese University of Hong Kong |
| Language | English |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, vi, 155 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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