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Synthetic studies of substituted 2,3-naphthalocyaninatozinc(II) complexes.

by Yee-On Yeung. / Thesis (M.Phil.)--Chinese University of Hong Kong, 1997. / Includes bibliographical references (leaves 76-80). / Acknowledgment --- p.i / Contents --- p.ii / List of Figures --- p.v / List of Tables --- p.vi / Abbreviations --- p.vii / Abstract --- p.viii / Chapter 1. --- Introduction --- p.1 / Chapter 2. --- Results and Discussion / Chapter 2.1 --- "Synthesis of Differently Substituted 2,3-Naphthalocyaninatozinc(II) Complexes" / Chapter 2.1.1 --- Preparation of substituted dicyanonaphthalenes --- p.13 / Chapter 2.1.2 --- "Preparation of octasubstituted 2,3-naphthalocyaninatozinc(II) complexes" --- p.16 / Chapter 2.1.3 --- "Aggregation of octasubstituted 2,3-naphthalocyaninatozinc(II) complexes" --- p.27 / Chapter 2.1.4 --- "Effects of substituents on the electronic spectra of 2,3- naphthalocyaninatozinc(II) complexes" --- p.31 / Chapter 2.2 --- "Synthetic Studies of Liquid Crystals Based on a 2,3-Naphthalocyanine Core" / Chapter 2.2.1 --- Preparation of dicyanonaphthalenes substituted with long side chains --- p.34 / Chapter 2.2.2 --- "Preparation of liquid crystals based on 2,3-naphthalocyanine cores" --- p.36 / Chapter 2.2.3 --- Characterization of the liquid crystals --- p.42 / Chapter 2.3 --- Conclusions --- p.46 / Chapter 3. --- Experimental Section / Chapter 3.1 --- Materials --- p.47 / Chapter 3.2 --- Physical Measurements --- p.47 / Chapter 3.3 --- "Preparation of (1,6,10,15,19,24,28,33-octamethyl-2,3-naphthalocyaninato)- zinc(II) (62)" --- p.48 / Chapter 3.4 --- "Preparation of (1,6,10,15,19,24,28,33-octahexyl-2,3-naphthalocyaninato)- zinc(II) (63)" --- p.51 / Chapter 3.5 --- "Preparation of (2,5,11,14,20,23,29,32-octahexyl-1,6,10,15,19,24,28,33- octamethyl-2,3-naphthalocyaninato)zinc(II) (67)" --- p.54 / Chapter 3.6 --- "Preparation of (2,5,11,14,20,23,29,32-octahexy1-2,3-naphthalocyaninato- zinc(II)complex (64)" --- p.58 / Chapter 3.7 --- "Preparation of (3,4,12,13,21,22,30,31-octapropylthio-2,3- naphthalocyaninato)zinc(II) (65)" --- p.60 / Chapter 3.8 --- "Preparation of (3,4,12,13,21,22,30,31 -octaphenylthio-2,3- naphthalocyaninato)zinc(II) (66)" --- p.63 / Chapter 3.9 --- "Preparation of [2,5,11,14,20,23,29,32-octa(hexyloxymethyl)-2,3- naphthalocyaninato]zinc(II) (79)" --- p.64 / Chapter 3.10 --- "Preparation of [2,5,11,14,20,23,29,32-octa(methoxybutyl-digol)-2,3- naphthalocyaninato]zinc(II) (80)" --- p.68 / Chapter 3.11 --- "Preparation of [2,5,11,14,20,23,29,32-octa(dodecylthiomethyl)-2,3- naphthalocyaninato]zinc(II) (81)" --- p.70 / Chapter 3.12 --- "Preparation of [3,4,12,13,21,22,30,31 -octa(octylthio)-2,3- naphthalocyaninato]zinc(II) (82)" --- p.72 / Chapter 3.13 --- "Preparation of [3,4,12,13,21,22,30,31-octa(dodecylthio)-2,3- naphthalocyaninato]zinc(II) (83)" --- p.74 / References --- p.76 / "Appendix A IR spectra of octasubstituted ZnNc complexes (62, 63, 64,66)." --- p.81 / Appendix B Mass spectra of octasubstituted ZnNc complexes (63-66). --- p.85 / Appendix C Determination of aggregation number (n) and aggregation constant (K). --- p.89 / Appendix D 1H NMR spectra of octasubstituted ZnNc complexes (80,81,83). --- p.90 / "Appendix E 13C NMR spectra of octasubstituted ZnNc complexes (80,82, 83)." --- p.93

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_321880
Date January 1997
ContributorsYeung, Yee-On., Chinese University of Hong Kong Graduate School. Division of Chemistry.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish
Detected LanguageEnglish
TypeText, bibliography
Formatprint, viii, 95 leaves : ill. (some col. mounted) ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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