by Chi-Hang Lee. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references (leaves 71-80). / Abstracts in English and Chinese. / ABSTRACT --- p.i / ACKNOWLEDGMENT --- p.iv / TABLE OF CONTENTS --- p.v / LIST OF SCHEMES --- p.vii / LIST OF FIGURES --- p.viii / LIST OF TABLES --- p.x / ABBREVIATIONS --- p.xi / Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Discovery of Phthalocyanines --- p.1 / Chapter 1.2 --- Synthesis of Phthalocyanines --- p.4 / Chapter 1.2.1 --- Metal-Free Phthalocyanines --- p.4 / Chapter 1.2.2 --- Metallophthalocyanines (MPcs) --- p.5 / Chapter 1.2.3 --- Sandwich Complexes (MPc2) --- p.7 / Chapter 1.2.4 --- Tetra-Substituted Phthalocyanines --- p.8 / Chapter 1.2.5 --- "2,3,9,10,16,17,23,24-Octa-substituted Phthalocyanines" --- p.11 / Chapter 1.2.6 --- "1,4,8,11,15,18,22,25-Octa-substituted Phthalocyanines" --- p.12 / Chapter 1.3 --- Mechanism for Phthalocyanine Formation --- p.14 / Chapter 1.4 --- Purification of Phthalocyanines --- p.16 / Chapter 1.5 --- Characteristics of Phthalocyanines --- p.17 / Chapter 1.5.1 --- Electronic Structure --- p.17 / Chapter 1.5.2 --- Absorption Spectra --- p.17 / Chapter 1.5.3 --- X-Ray Diffraction Studies --- p.19 / Chapter 1.6 --- Applications of Phthalocyanines --- p.20 / Chapter 1.6.1 --- Colorants --- p.20 / Chapter 1.6.2 --- Photodynamic Therapy --- p.21 / Chapter 1.6.3 --- Catalysis --- p.22 / Chapter 2 --- Results and Discussion --- p.23 / Chapter 2.1 --- "Preparation, Spectroscopic Properties, and Structure of Phthalocyanines Substituted with Four 2,4-Dimethyl-3- pentyloxy Moieties" --- p.23 / Chapter 2.1.1 --- Synthetic Studies --- p.24 / Chapter 2.1.2 --- UV-Vis Spectra --- p.28 / Chapter 2.1.2.1 --- Effects of Metal Center --- p.28 / Chapter 2.1.2.2 --- Effects of Substituents --- p.30 / Chapter 2.1.2.3 --- Effects of Concentration --- p.30 / Chapter 2.1.2.4 --- Absorption Spectra of MnClPc(OC7H15)4 (10) --- p.34 / Chapter 2.1.3 --- 1H NMR Spectra --- p.35 / Chapter 2.1.4 --- Structural Studies --- p.38 / Chapter 2.1.4.1 --- Molecular Structures of ZnPc(OC7H15)4 (3) and CoPC(OC7H15)4 (5) --- p.39 / Chapter 2.1.4.2 --- Molecular Structure of MnClPc(OC7H15)4 (10) --- p.41 / Chapter 2.2 --- Formation and Crystal Structures of Novel Inclusion Complexes of Phthalocyanines and Oxalic Acid --- p.43 / Chapter 2.2.1 --- 1:1Complex with Metal-free Phthalocyanine (8) --- p.43 / Chapter 2.2.2 --- 1:1Complexes with Palladium Phthalocyanine (4) --- p.49 / Chapter 2.2.3 --- Conclusion --- p.51 / Chapter 2.3 --- Cerium Promoted Formation of Metal-Free Phthalocyanines --- p.52 / Chapter 2.3.1 --- Introduction --- p.52 / Chapter 2.3.2 --- Preparation of Metal-free Phthalocyanines --- p.52 / Chapter 2.3.3 --- Conclusion --- p.58 / Chapter 3 --- Experimental --- p.59 / Chapter 3.1 --- General --- p.59 / Chapter 3.2 --- "Synthesis of 3-(2,4-dimethyl-3-pentyloxy)phthalonitrile (2)" --- p.60 / Chapter 3.3 --- "Synthesis of ZnPc(OC7H,5)4 (3 and 6)" --- p.61 / Chapter 3.4 --- Synthesis of PdPc(OC7H15)4 (4 and 7) --- p.62 / Chapter 3.5 --- Synthesis of CoPc(OC7H15)4 (5) --- p.64 / Chapter 3.6 --- Synthesis of H2Pc(OC7H15)4 (8) --- p.64 / Chapter 3.7 --- Synthesis of MnClPc(OC7H15)4 (10) --- p.66 / Chapter 3.8 --- General Procedure for the Cerium-Promoted Cyclization of Phthalonitriles --- p.67 / Chapter 3.9 --- X-ray Crystallographic Analyses --- p.69 / Chapter 4 --- REFERENCES --- p.71 / APPENDIX A lH and13 C̐ưث1H} NMR spectra / APPENDIX B X-ray Crystallographic Data
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_323821 |
| Date | January 2002 |
| Contributors | Lee, Chi-Hang., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xii, 80, [32] leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
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