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Synthetic studies of sesquiterpenoid furanoeudesmanes.

Tsang Tsun-keung. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2002. / Includes bibliographical references (leaves 73-78). / Abstracts in English and Chinese. / ACKNOWLEDGEMENTS --- p.i / CONTENTS --- p.ii / ABSTRACT --- p.iv / ABBREVIATIONS --- p.vii / Chapter CHAPTER 1 --- INTRODUCTION --- p.1 / Chapter 1.1 --- General Background --- p.1 / Chapter 1.1.1 --- Characteristics of sesquiterpenoid furanoeudesmanes --- p.1 / Chapter 1.1.2 --- Examples of trans-fused natural sesquiterpenoid furanoeudesmanes --- p.2 / Chapter 1.1.3 --- Examples of cis-fused natural sesquiterpenoid furanoeudesmanes --- p.3 / Chapter 1.1.3.1 --- Tubipofuran and 15-acetoxytubipofuran --- p.3 / Chapter 1.1.4 --- Examples of C9-C10 unsaturated natural sesquiterpenoid furanoeudesmanes --- p.6 / Chapter 1.2 --- Biosynthesis of Sesquiterpenoid Furanoeudesmanes --- p.7 / Chapter 1.3 --- Synthesis of Sesquiterpenoid Furanoeudesmanes --- p.9 / Chapter 1.3.1 --- Synthetic examples of trans-fused sesquiterpenoid furanoeudesmanes --- p.9 / Chapter 1.3.2 --- Synthetic examples of cis-fused sesquiterpenoid furanoeudesmanes --- p.10 / Chapter 1.3.2.1 --- "Linearly fused A/B trans- and A/B cis- furo[3,2-b] and furo[2,3-b] decalin derivatives" --- p.10 / Chapter 1.3.2.2 --- "(±)-14-Norfuranoeudesmane-4,5-dione" --- p.11 / Chapter 1.3.2.3 --- Tubipofuran and 15-acetoxytubipofuran --- p.12 / Chapter CHAPTER 2 --- RESULTS AND DISCUSSION --- p.18 / Chapter 2.1 --- Aim of Present Work --- p.18 / Chapter 2.2 --- C ring + A ring →AC ring → ABC ring Scheme A --- p.20 / Chapter 2.2.1 --- Preparation of C ring in Scheme A --- p.20 / Chapter 2.2.2 --- Preparation of A ring in Scheme A --- p.22 / Chapter 2.2.3 --- Formation of B ring in Scheme A --- p.26 / Chapter 2.3 --- C ring + A ring → AC ring → ABC ring Scheme B --- p.37 / Chapter 2.3.1 --- Preparation of C ring in Scheme B --- p.37 / Chapter 2.3.2 --- Preparation of A ring in Scheme B --- p.37 / Chapter 2.3.3 --- Formation of B ring in Scheme B --- p.38 / Chapter CHAPTER 3 --- CONCLUSION --- p.51 / Chapter CHAPTER 4 --- EXPERIMENTAL SECTION --- p.52 / REFERENCES --- p.73 / APPENDIX --- p.79 / Chapter I --- List of X-ray Crystallographic Data / Chapter II --- List ofNMR Spectra

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_323894
Date January 2002
ContributorsTsang, Tsun-keung., Chinese University of Hong Kong Graduate School. Division of Chemistry.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, viii, 107 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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