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Enhancement of photocatalytic activity by doping nitrogen and boron into titanium dioxide.

Leung Cheuk-wan. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2006. / Includes bibliographical references. / Abstracts in English and Chinese. / Abstract --- p.i / Abstract (Chinese) --- p.ii / Acknowledgement --- p.iii / Table of Contents --- p.v / Lists of Tables --- p.ix / Lists of Figures --- p.x / Chapter Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- TiO2 Photocatalysis --- p.1 / Chapter 1.1.1 --- Mechanisms of TiO2 Photocatalysis --- p.1 / Chapter 1.2 --- Visible Light Photocatalyst --- p.4 / Chapter 1.2.1 --- Preparation of Visible Light Ti02 Photocatalysts --- p.5 / Chapter 1.2.1.1 --- Dye Sensitization --- p.5 / Chapter 1.2.1.2 --- Metal Doping --- p.6 / Chapter 1.2.1.3 --- Coupling of Semiconductors --- p.6 / Chapter 1.2.1.4 --- Nonmetal Doping --- p.7 / Chapter 1.3 --- Enhanced TiO2 Photocatalytic Activity under UV Light --- p.8 / Chapter 1.3.1 --- Preparation of TiO2 Photocatalyst with Enhanced Activity in UV Light --- p.8 / Chapter 1.3.1.1 --- Loading of Metal --- p.8 / Chapter 1.3.1.2 --- Impurity Co-doping --- p.9 / Chapter 1.3.1.3 --- Morphological Control --- p.10 / Chapter 1.3.1.4 --- Increasing Surface Area --- p.10 / Chapter 1.4 --- Summary --- p.11 / Chapter 1.6 --- Aim of This Research and its Significance --- p.12 / Chapter 1.7 --- References --- p.13 / Chapter Chapter 2 --- Preparation of N-doped TiO2 with Enhanced Surface Area: A Detailed Characterization and Mechanism --- p.19 / Chapter 2.1 --- Introduction --- p.19 / Chapter 2.2 --- Experimental --- p.21 / Chapter 2.2.1 --- Materials and Catalyst Preparation --- p.21 / Chapter 2.2.2 --- Characterization --- p.21 / Chapter 2.2.3 --- Photocatalytic Activity --- p.23 / Chapter 2.3 --- Results and Discussion --- p.24 / Chapter 2.3.1 --- XRD Analysis --- p.24 / Chapter 2.3.2 --- UV-Vis Absorption Spectroscopy and Bandgap Energies --- p.27 / Chapter 2.3.3 --- N2 Sorption Analysis --- p.29 / Chapter 2.3.4 --- SEM Analysis --- p.33 / Chapter 2.3.5 --- TEM Analysis --- p.35 / Chapter 2.3.6 --- FT-IR Spectroscopy --- p.36 / Chapter 2.3.7 --- Raman Spectroscopy --- p.39 / Chapter 2.3.8 --- XPS Studies --- p.44 / Chapter 2.3.9 --- PL Measurements --- p.49 / Chapter 2.3.10 --- Photocatalytic Activity Measurements --- p.50 / Chapter 2.3.11 --- Advantages of Using Urea as a N-doping Source --- p.54 / Chapter 2.3.12 --- Mechanisms for N-doping --- p.56 / Chapter 2.4 --- Conclusions --- p.58 / Chapter 2.5 --- References --- p.59 / Chapter Chapter 3 --- Preparation of Nanoporous Interstitial B-doped TiCO2 with Enhanced Photocatalytic Activity --- p.63 / Chapter 3.1 --- Introduction --- p.63 / Chapter 3.2 --- Experimental --- p.65 / Chapter 3.2.1 --- Materials and Catalyst Preparation --- p.65 / Chapter 3.2.2 --- Characterization --- p.66 / Chapter 3.2.3 --- Photocatalytic Activity --- p.67 / Chapter 3.3 --- Results and Discussion --- p.68 / Chapter 3.3.1 --- XRD Analysis --- p.68 / Chapter 3.3.2 --- UV-Vis Absorption Spectroscopy and Bandgap Energies --- p.71 / Chapter 3.3.3 --- N2 Sorption Analysis --- p.73 / Chapter 3.3.4 --- SEM and TEM --- p.76 / Chapter 3.3.5 --- FT-IR Spectroscopy --- p.80 / Chapter 3.3.6 --- Raman Spectroscopy --- p.82 / Chapter 3.3.7 --- PL Measurements --- p.84 / Chapter 3.3.8 --- XPS Studies --- p.85 / Chapter 3.3.9 --- Photocatalytic Activity Measurements --- p.89 / Chapter 3.3.10 --- State and Form of Boron in TiO2 Lattice and its Effects --- p.91 / Chapter 3.4 --- Conclusions --- p.93 / Chapter 3.5 --- References --- p.94 / Chapter Chapter 4 --- Conclusions --- p.97

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_325734
Date January 2006
ContributorsLeung, Cheuk-wan., Chinese University of Hong Kong Graduate School. Division of Environmental Science.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, xiii, 97 leaves : ill. (some col.) ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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