Chan, Ka Po. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2007. / Includes bibliographical references. / Abstracts in English and Chinese. / Table of contents --- p.vi / Acknowledgements --- p.i / Abstract --- p.ii / 摘要 --- p.iv / List of Compounds Synthesized --- p.xi / Abbreviation --- p.xii / Chapter Chapter 1 --- Synthesis and characterization of pyrazyl-Iinked bis(phosphoranoimido) main group 14 and 13 metal complexes / Chapter 1.1 --- Introduction --- p.1 / Chapter 1.1.1 --- A general review of phosphoranoimine ligands --- p.1 / Chapter 1.1.2 --- A general review of group 14 metal complexes containing phosphoranoimine ligands --- p.8 / Chapter 1.1.3 --- A general review of group 13 metal complexes containing phosphoranoimine ligands --- p.10 / Chapter 1.2 --- Objectives --- p.12 / Chapter 1.3 --- Results and Discussion --- p.14 / Chapter 1.3.1.1 --- Synthesis of pyrazyl-Iinked bis(phosphoranoimine) (Me3SiN=PPr'2CH2)2C4H2N2-2，3 (35) and dilithium compound [{Li(THF)2(Me3SiNPPr'2CH)}2C4H2N2-2，3}] (36) --- p.14 / Chapter 1.3.1.2 --- Spectroscopic properties of 35 and 36 --- p.15 / Chapter 1.3.1.3 --- "Molecular structure of [{Li(THF)2(Me3SiNPPr'2CH)}2C4H2N2-2,3}] (36)" --- p.16 / Chapter 1.3.2.1 --- Synthesis of stannacyclopentane [Sn{C(H)(Pr')2P=N(SiMe3)}2C4H2N2-2，3] (37) and chlorostannylene [{Sncl(Me3SiNPPr'2CH)}2C4H2N2-2，3] (38) --- p.20 / Chapter 1.3.2.2 --- Spectroscopic properties of 37 and 38 --- p.20 / Chapter 1.3.2.3 --- "Molecular structures of [Sn{C(H)(Pr')2P=N(SiMe3)}2C4H2N2-2,3] (37) and [{SnCl(Me3SiNPPr'2CH)}2C4H2N2-2,3] (38)" --- p.22 / Chapter 1.3.3.1 --- "Synthesis of asymmetric lead(II) enamido and chloro compound [{PbCl(Me3SiNPPr'2CH)}C4H2Nr2，3-(CHPPr'2Me3SiN)Pb(Me3SiN PPr'2C)C4H2N2-2,3-(CHPr'2P=NSiMe3)] (39)" --- p.28 / Chapter 1.3.3.2 --- Spectroscopic properties of 39 --- p.30 / Chapter 1.3.3.3 --- "Molecular structure of [{Pbcl(Me3SiNPPr'2CH)}C4H2N2-2,3-(CHPPr'2Me3SiN)Pb(Me3SiN PPr'2C)C4H2N2-2，3-(CHPr'2P=NSiMe3)] (39)" --- p.30 / Chapter 1.3.4.1 --- Synthesis of polymeric dilithiated cyclic germylene [Ge{C(Pr')2PN(SiMe3)Li(THF)}2(02C4H8)C4H2N2-2，3] (40) --- p.35 / Chapter 1.3.4.2 --- Spectroscopic properties of 40 --- p.37 / Chapter 1.3.4.3 --- Molecular structure of [Ge{C(Pr')2PN(SiMe3)Li(THF)}2(02C4H8)C4H2N2-2，3] (40) --- p.37 / Chapter 1.3.5.1 --- "Synthesis of bis(trimethylsilyl)amido metal compounds [{Sn{N(SiMe3)2}(Me3SiNPPr'2CH)}2C4H2N2-2,3] (41) and [{Pb{N(SiMe3)2}(Me3SiNPPr'2CH)} C4H2N2-2，3{Pb(CHPr'2P= NSiMe3){N(SiMe3)2}}](42)" --- p.41 / Chapter 1.3.5.2 --- Spectroscopic properties of 41 and 42 --- p.42 / Chapter 1.3.5.3 --- Molecular structures of [{Sn{N(SiMe3)2}(Me3SiNPPr'2CH)}2C4H2N2-2，3] (41) and [{Pb{N(SiMe3)2}(Me3SiNPPr'2CH)}C4H2Nr2，3{Pb(CHPr'2P= NSiMe3){N(SiMe3)2}}](42) --- p.43 / Chapter 1.3.6.1 --- "Synthesis of pyrazyl-linked bis(phosphoranoimido) group 13 metal compounds [{MCl2(Me3SiNPPr'2CH)}2C4H2N2-2，3] (M=A1 (43)， Ga (44)) and [{AlMe2(Me3SiNPPr'2CH)}2C4H2N2-2,3] (45)" --- p.49 / Chapter 1.3.6.2 --- "Spectroscopic properties of 43, 44 and 45" --- p.50 / Chapter 1.3.6.3 --- "Molecular structures of[{MCl2(Me3SiNPPr'2CH)}2C4H2N2-2,3] (M=A1 (43), Ga (44)) and [{AlMe2(Me3SiNPPr'2CH)}2C4H2N2-2,3] (45)" --- p.50 / Chapter 1.4 --- Experimental Section --- p.57 / Chapter 1.5 --- References for chapter 1 --- p.67 / Chapter Chapter 2 --- Reactivity of pyrazyl-Iinked bis(phosphoranoimido) heteroleptic stannylenes / Chapter 2.1 --- Introduction --- p.73 / Chapter 2.1.1 --- A general review of heteroleptic stannylenes --- p.73 / Chapter 2.2 --- Objectives --- p.80 / Chapter 2.3 --- Results and Discussion --- p.81 / Chapter 2.3.1.1 --- "Reaction of 38 with sodium cyclopentadienide: synthesis of [{Sn(η1-C5H5)(Me3SiNPPr'2CH)}2C4H2N2-2,3] (70)" --- p.81 / Chapter 2.3.1.2 --- Spectroscopic properties of 70 --- p.81 / Chapter 2.3.1.3 --- "Molecular structure of [{Sn(η1-C5H5)(Me3SiNPPr'2CH)}2C4H2N2-2,3] (70)" --- p.83 / Chapter 2.3.2.1 --- "Reaction of 41 with 3,5-di-tert-butyl-o-benzoquinone: synthesis of [{Sn{0(2,4-di-Bu1-C6H2)0}{N(SiMe3)2}(Me3SiNPPr'2CH)}2 C4H2N2-2,3] (71)" --- p.86 / Chapter 2.3.2.2 --- Spectroscopic properties of 71 --- p.87 / Chapter 2.3.2.3 --- "Molecular structure of [{Sn{0(2´ة4-di-Bu'-C6H2)0}{N(SiMe3)2}(Me3SiNPPr'2CH)}2 C4H2N2-2,3] (71)" --- p.88 / Chapter 2.4 --- Experimental Section --- p.91 / Chapter 2.5 --- References for chapter 2 --- p.93 / Chapter Chapter 3 --- "Synthesis, characterization and catalytic study of pyrazyl-linked bis(phosphoranoimido) group 4 early transition metal complexes" / Chapter 3.1 --- Introduction --- p.96 / Chapter 3.1.1 --- A general review of group 4 early transition metal complexes containing phosphoranoimine ligands --- p.96 / Chapter 3.1.2 --- A general review of olefin polymerization with group 4 metallocene catalysts --- p.99 / Chapter 3.2 --- Results and Discussion --- p.101 / Chapter 3.2.1.1 --- "Synthesis and characterization of pyrazyl-linked bis(phosphoranoimido)chloro group 4 transition metal compounds [{MCl3(Me3SiNPPr'2CH)}2C4H2N2-2,3] [M = Zr (72)，Hf (73)]" --- p.101 / Chapter 3.2.1.2 --- Spectroscopic properties of 72 and 73 --- p.101 / Chapter 3.2.1.3 --- "Molecular Structure of [{HfCl3(Me3SiNPPr'2CH)}2C4H2N2-2,3] (73)" --- p.102 / Chapter 3.2.2.1 --- "Synthesis and characterization of pyrazyl-linked bis(phosphoranoimido)amido group 4 transition metal compounds [μ-M(NMe2)2(Me3SiNPPr'2CH)C4H2N2-2,3(CHPPr'2NSiMe3) M(NMe2)3]2 [M = Zr (74), Hf (75)]" --- p.105 / Chapter 3.2.2.2 --- Spectroscopic properties of 74 and 75 --- p.106 / Chapter 3.2.2.3 --- "Molecular Structure of [μ-Zr(NMe2)2(Me3SiNPPr'2CH)C4H2N2- 2,3(CHPPr'2NSiMe3)Zr(NMe2)3]2 (74)" --- p.107 / Chapter 3.2.3.1 --- Catalytic studies of compounds 72-75 on ethylene polymerization --- p.110 / Chapter 3.3 --- Experimental Section --- p.112 / Chapter 3.4 --- References for chapter 3 --- p.116 / Appendix I / Chapter A. --- General Procedures --- p.118 / Chapter B. --- Spectroscopic and physical measurements --- p.118 / Appendix II / Table A.1. Selected crystallographic data for compounds 36-39 --- p.121 / Table A.2. Selected crystallographic data for compounds 40-43 --- p.122 / "Table A.3. Selected crystallographic data for compounds 44, 45, 70 and 71" --- p.123 / Table A.4. Selected crystallographic data for compounds 73 and 74 --- p.124
| Identifer | oai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_325985 |
| Date | January 2007 |
| Contributors | Chan, Ka Po., Chinese University of Hong Kong Graduate School. Division of Chemistry. |
| Source Sets | The Chinese University of Hong Kong |
| Language | English, Chinese |
| Detected Language | English |
| Type | Text, bibliography |
| Format | print, xiii, 124 leaves : ill. ; 30 cm. |
| Rights | Use of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/) |
Page generated in 0.0021 seconds