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Synthesis, structural characterization and electrochemistry of 13-vertex carboranes and their radical anions.

Fu, Xiaodu. / Thesis (M.Phil.)--Chinese University of Hong Kong, 2008. / Includes bibliographical references (leaves 93-102). / Abstracts in English and Chinese. / Acknowledgement --- p.I / Abstract (in English) --- p.II / Abstract (in Chinese) --- p.III / Abbreviation --- p.IV / List of Compounds --- p.V / List of Figures --- p.VII / Contents --- p.X / Chapter Chapter 1 --- Introduction --- p.1 / Chapter 1.1 --- Carboranes --- p.1 / Chapter 1.2 --- "C,C'-Linked 12-Vertex Carborane Anions" --- p.10 / Chapter 1.3 --- 13-Vertex closo-Carboranes --- p.13 / Chapter 1.4 --- 13-Vertex nido-Carborane Salts and 14-Vertex closo-Carboranes --- p.16 / Chapter 1.5 --- Carborane Radical Anions --- p.19 / Chapter 1.6 --- Our Objectives --- p.23 / Chapter Chapter 2 --- 13-Vertex Carboranes --- p.24 / Chapter 2.1 --- Synthesis and Characterization of 13-Vertex closo-Carboranes --- p.24 / Chapter 2.2 --- Molecular Structures of II-4 and II-6 --- p.30 / Chapter 2.3 --- Attempts to prepare 13-vertex carboranes with propenyl bridges --- p.33 / Chapter 2.4 --- Summary --- p.35 / Chapter Chapter 3 --- 13-Vertex Carborane Radical Anions --- p.36 / Chapter 3.1 --- Synthesis --- p.36 / Chapter 3.2 --- Structures --- p.41 / Chapter 3.3 --- Synthesis and Structure of a monoanionic salt --- p.46 / Chapter 3.4 --- Summary --- p.50 / Chapter Chapter 4 --- Electrochemical Study of 12- and 13-Vertex closo-Carboranes --- p.51 / Chapter 4.1 --- Electrochemical Study of 12-Vertex Carboranes --- p.51 / Chapter 4.2 --- Electrochemical Study of 13-Vertex Supercarboranes --- p.61 / Chapter 4.3 --- Summary --- p.74 / Chapter Chapter 5 --- Conclusion --- p.75 / Chapter Chapter 6 --- Experimental Section --- p.77 / References --- p.93 / Appendix / Chapter I. --- Publication Based on the Research Findings --- p.103 / Chapter II. --- Crystal Data and Summary of Data Collection and Refinement --- p.104 / Chapter III. --- X-ray crystallographic data in CIF (electronic form)

Identiferoai:union.ndltd.org:cuhk.edu.hk/oai:cuhk-dr:cuhk_326534
Date January 2008
ContributorsFu, Xiaodu., Chinese University of Hong Kong Graduate School. Division of Chemistry.
Source SetsThe Chinese University of Hong Kong
LanguageEnglish, Chinese
Detected LanguageEnglish
TypeText, bibliography
Formatprint, xi, 105 leaves : ill. ; 30 cm.
RightsUse of this resource is governed by the terms and conditions of the Creative Commons “Attribution-NonCommercial-NoDerivatives 4.0 International” License (http://creativecommons.org/licenses/by-nc-nd/4.0/)

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