The complex formation of UO(,2)('+2), Ca('+2) and Th('+4) with halates, acetate and haloacetates has been studied by means of solvent extraction. The stability constants have been determined for UO(,2)('+2), Ca('+2) and Th('+4) with halates, acetate and haloacetates at 25(DEGREES)C. The enthalpies were determined by titration calorimetry. From the value of the enthalpy and entropy, model were developed for assignment of relative inner vs outer sphere character to the complexes. It has been found that inner sphere character increases with the charge density of the cation and with the pka of the ligands. / Source: Dissertation Abstracts International, Volume: 43-03, Section: B, page: 0719. / Thesis (Ph.D.)--The Florida State University, 1982.
| Identifer | oai:union.ndltd.org:fsu.edu/oai:fsu.digital.flvc.org:fsu_74804 |
| Contributors | KHALILI, FAWWAZ IZZAT., Florida State University |
| Source Sets | Florida State University |
| Detected Language | English |
| Type | Text |
| Format | 139 p. |
| Rights | On campus use only. |
| Relation | Dissertation Abstracts International |
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