Ph.D. (Theoretical Physics) / In this thesis the thermodynamic and magnetic properties of the non-degenerate Hubbard model are investigated. The underlying lattice is the bcc-lattice. The results obtained will therefore be especially applicable to systems with a single, narrow conduction band. As a check the thermodynamic properties of the model system are first calculated in two limiting cases, namely the free electron 'gas and the strong coupling limit. In this process, use is made of results related to Wick's Theorem, which are developed in an appendix. Another check is provided by the calculation of the ground state spectrum of a finite, fourpoint system. These results are obtained using standard group theory techniques. The ground state for the non-degenerate Hubbard model is solved approximatively by a variational method. Once again the necessary version of Wick's theorem is developed in an appendix. The ,results for the neutral case (i.e. a half-filled band) is in agreement with other studies on AB-lattices: It is found that the system is anti ferromagnetic for all values of the coupling constant. The quarter and three-quarter filled cases, hitherto not studied because of numerical complexity, yield a completely different picture. For increasing values of the coupling constant second order phase transitions are found, first from the para- to the ferromagnetic phase and then from the ferro- to the anti ferromagnetic phase. The only results available in the literature related to this case were obtained for an almost half-filled band in the strong-coupling limit and qualitatively support the findings of the present study. It is proposed that the simple theory used in this study be extended for use in physical systems such as Cr.
| Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:uj/uj:11506 |
| Date | 11 June 2014 |
| Creators | Villet, Charles Mathurin |
| Source Sets | South African National ETD Portal |
| Detected Language | English |
| Type | Thesis |
| Rights | University of Johannesburg |
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