M.Sc. (Chemistry) / A new method has been developed for the conversion of carbohydrate vicinal diols into the corresponding glycal derivatives. Treatment of suitably protected furanose 1,2-diols with mesyl chloride and triethylamine in anhydrous 1,2-dirnethoxyethane resulted in the formation of 2-0-mesyl-furanosyl chlorides. Reductive elimination of the latter with excess active zinc dust in the presence of iodide furnished furanoid glycals ...
| Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:uj/uj:14391 |
| Date | 21 October 2015 |
| Source Sets | South African National ETD Portal |
| Detected Language | English |
| Type | Thesis |
| Rights | University of Johannesburg |
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