First-principle modelling of chemical processes and their unit operations has been
of great interest in the chemical process, as well as the control and allied industries
over the past decades. This is because it offers the opportunity to develop virtual
representations (models) of real process systems, which can be used to describe and
predict the dynamic behaviour of those systems. These models are based on the
fundamentals of the transport phenomena of fluid dynamics (involving momentum
transfer), mass transfer, and energy transfer of the systems they describe.
A first-principle model of a semi-batch rhodium dissolution chemical process
has been developed. It describes the dynamic behaviour of two exothermic reactions,
occurring simultaneously in a semi-batch process. The dissolution of 29 kg
of solid crude rhodium sponge (Rh) into 546 L of a solution of hydrochloric acid
(HCl(aq)), to produce a solution of aqueous rhodium(III) chloride (RhCl3.H2O),
as well as the reaction of chlorine (Cl2(aq)) with water (H2O(l)) to produce some
more HCl(aq) in the reactor. The model was formulated as a system of explicit ordinary
differential equations (ODEs), which demonstrated some good and stable
qualitative tracking of the temperature and pressure data of the real reactor. The
molar responses of all chemical species, as well as the heats of reactions, showed to
be consistent with the description of the process, and no negative values of those
variables were generated.
Estimates of the key parameters of heat and mass transfer coefficients, arrhenius
constants, and activation energies of reactions were assumed and tuned to satisfaction
by trial-and-error, but not optimised. This is because during simulations, the
numerical solver would often fail to integrate the equations, due to the appearance
of large derivatives in some model equations whenever those parameters varied,
thereby stopping simulations.
Finally, the model was validated with a set of data from 45 batches. For all
simulations done, the simulated temperature responses showed better prediction
of data than the simulated pressure responses did, with an average percentage
accuracy of 80% against 60 percent, respectively. / Dissertation (MSc)--University of Pretoria, 2017. / Anglo American Platinum / BluESP (Pty) Ltd / Chemical Engineering / MSc / Unrestricted
| Identifer | oai:union.ndltd.org:netd.ac.za/oai:union.ndltd.org:up/oai:repository.up.ac.za:2263/64414 |
| Date | January 2017 |
| Creators | Nkoghe Eyeghe, Norbertin |
| Contributors | Sandrock, Carl, xnorbertin002@yahoo.fr |
| Publisher | University of Pretoria |
| Source Sets | South African National ETD Portal |
| Language | English |
| Detected Language | English |
| Type | Dissertation |
| Rights | © 2018 University of Pretoria. All rights reserved. The copyright in this work vests in the University of Pretoria. No part of this work may be reproduced or transmitted in any form or by any means, without the prior written permission of the University of Pretoria. |
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