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Istraživanje fenomena aerosola formiranog od emulzija mineralnih i drugih ulja u vodi / Investigation on the phenomena of aerosols formed from emulsions of mineral and other oils in water

<p>Predmet istraživanja ove doktorske disertacije<br />je bio formiranje i proučavanje osobina i<br />pona&scaron;anja organskih aerosola nastalih<br />atomiziranjem stabilnih emulzija dominantno<br />pod dejstvom centrifugalne sile. Kori&scaron;ćene su<br />vodene emulzije komercijalnih sredstava za<br />hlađenje i podmazivanje (SHP), koja se koriste<br />pri obradi metalnih odlivaka. Cilj istraživanja je<br />bio ispitati i objasniti uticaj koncentracije SHP<br />emulzije, brzine strujanja vazduha, prirode kako<br />ulja, tako i osobina emulzija, kao &scaron;to su gustina,<br />viskoznost, povr&scaron;inski napon, kao i udaljenost<br />od mesta atomiziranja na masenu koncentraciju,<br />broj i veličinu kapi aerosola u kontrolisanim<br />laboratorijskim uslovima.<br />Uslovi eksperimenta isključili su uticaj toplote<br />nastale kao posledica trenja alata i delova koji<br />se obrađuju. Pored toga isključeno je prisustvo<br />čvrstih mikronskih čestica koje potiču od delova<br />koji se obrađuju, kao i prisutvo plivajućeg<br />hidrauličnog ulja i mikroorganizama koji uvek<br />prate realan industrijski fluid.<br />Eksperimentalni program je realizovan na tri<br />komercijalna SHP sredstva različitog porekla.<br />Proučavani su aerosoli formirani atomiziranjem<br />emulzije tri različite koncentracije uljne faze: 1,<br />6 i 10 %. Pri jednakim eksperimentalnim<br />uslovima ispitivan je i aerosol formiran, od<br />vode kori&scaron;ćene za pripremu emulzija. Određene<br />su osobine ulja i emulzija koje su od značaja za<br />atomiziranje tečnosti. Proučavan je i uticaj<br />brzine ventilacionog vazduha na osobine<br />aerosola. Eksperimenti su realizovani pri<br />brzinama vazduha od 1, 3, 6, 8 m/s.<br />Uzorkovanje aerosola je realizovano u komori,<br />na ulazu u ventilacini vod i duž ventilacione<br />cevi dužine 8m na pet mernih tačaka koje se<br />nalaze na 0,5, 1, 2, 4, 6, 8 m u odnosu na<br />komoru.<br />Značajan doprinos ove doktorske disertacije je<br />postavljanje teorije da atomiziranjem emulzije<br />kao heterogene tečnosti, nastaje heterogen<br />aerosol, pri čemu mogu nastati kapi različite<br />prirode, između ostalog i kapi čistog ulja. Na taj<br />način je obja&scaron;njen fenomen da porastom<br />koncentracije emulzije raste veličina kapi<br />nastalog aerosola. Aerosoli nastali od<br />koncentrovanijih emulzija pokazuju uređenije<br />strujanje kroz ventilacionu cev, &scaron;to je od<br />značaja za uspe&scaron;nije projektovanje ventilacionih<br />sistema i filtara za njihovu separaciju u cilju<br />za&scaron;tite zdravlja radnika i za&scaron;tite okoline.</p> / <p> This PhD Thesis presents an experimental<br /> study of organic aerosols formed from stable<br /> water emulsions, predominantly by centrifugal<br /> force under laboratory conditions. Emulsions of<br /> metalworking fluids (MWF) were used in the<br /> experiments. The aim of this investigation was<br /> to explain the influence of MWF emulsion<br /> concentration, oil and emulsion properties<br /> (density, viscosity, and surface tension), air<br /> velocity, as well as distance from atomization<br /> generator on aerosol behavior and properties as<br /> size distribution, mass and number<br /> concentration. The experimental conditions<br /> excluded the influence of the heat arising from<br /> the friction between the tool and the<br /> workpieces. In this way the mechanism of<br /> aerosol formation by the<br /> evaporation/condensation is minimized.<br /> Besides, the presence of solid micrometer sized<br /> particulates originated from the work piece is<br /> excluded, as well as the presence of tramp oil<br /> and microorganisms, always accompanying a<br /> real industrial fluid.<br /> Three different commercial MWFs were<br /> investigated at three different oil-in-water<br /> emulsion concentrations, 1, 6, and 10 %<br /> respectively. Water aerosol was investigated<br /> under same experimental conditions. Properties<br /> of MWF oils and emulsion, which are important<br /> for liquid atomization, were determined.<br /> Influence of ventilation air velocity on aerosol<br /> properties was investigated as well.<br /> Experiments were realized under four different<br /> air velocities: 1, 3, 6, and 8 m/s. Samples were<br /> taken at three different points: at the camber, at<br /> the entrance of ventilation pipe, and at five<br /> sampling points along the pipe. Ventilation pipe<br /> was 8 m long, and sampling point were at 0.5, 1,<br /> 2, 4, 6, 8 m from the aerosol camber.<br /> The main contribution of this dissertation is<br /> the new theory that atomization of emulsion as a<br /> heterogeneous fluid leads to the formation of<br /> heterogeneous aerosol, containing droplets of a<br /> different nature, including droplets of pure oil.<br /> This theory explains the phenomenon that the<br /> aerosol droplet sizes increase with the increase<br /> of the emulsion concentration. Obtained results<br /> show that aerosols formed from the emulsions<br /> of higher concentration (6 and 10 %) have less<br /> chaotic flow through the ventilation pipe. This<br /> observation is important for better design of<br /> ventilation systems and filters for mist<br /> separation in order to protect human health and<br /> the environment.&nbsp;</p>

Identiferoai:union.ndltd.org:uns.ac.rs/oai:CRISUNS:(BISIS)77259
Date17 May 2012
CreatorsSokolović Dunja
ContributorsZavargo Zoltan, Marinković-Nedučin Radmila, Cakić Milorad, Dugić Pero
PublisherUniverzitet u Novom Sadu, Tehnološki fakultet Novi Sad, University of Novi Sad, Faculty of Technology at Novi Sad
Source SetsUniversity of Novi Sad
LanguageSerbian
Detected LanguageEnglish
TypePhD thesis
Formatapplication/pdf

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